Znucalite

CaZn11(UO2)(CO3)3(OH)20 · 4H2O
IMA status
  • Approved
IMA symbol
Znu
Discovered
1989
IMA approved
1989
Also known as
  • IMA1989-033
  • Znucaliet

Where it forms, where it's found

Geological setting

Oxidation product on uraninite-bearing dump material.

Type locality
Lill Mine
  1. Černojamské deposit
  2. Březové Hory
  3. Příbram
  4. Příbram District
  5. Central Bohemian Region
  6. Czech Republic

49.6969°, 14.0003°

10recorded occurrences
Source · OpenStreetMap

Radioactivity

Physical

Transparency
Translucent
Colour
White to light yellow
Streak
White
Cleavage
Perfect

(010)

Density
3.01 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 50 – 66° · 2V calc = 66.4°
Refractive index
1.556 – 1.621
Surface relief
Moderate
Principal indices
nα 1.556 – 1.563 · nβ 1.600 · nγ 1.620 – 1.621
Dispersion
strong
Extinction
Extinction inclined about 9° (type description) Parallel extinction (Mas d'Alary, France)
UV response
Yellow-green fluorescence with SW and LW UV (from type loc). Not fluorescent (from Mas d'Alary).
Notes

X = c; Y = b; Z = a. Negative elongation. Type description gives β = 1.620 and 2V (calculated) = 0.

Michel-Lévy diagramhighlighted lineδ = 0.0610
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]610 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation610 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/m
Cell parameters
a = 10.722(2) Å · b = 6.259(1) Å · c = 25.355(1) Å
Cell angles
β = 101.13(1) °
Ratio a:b:c
1 : 0.584 : 2.365
Z
2
Morphology

Crystals are thin lamellar, to 100 µm, in spherical boxworklike aggregates; forms coatings. From Mas d'Alary, France, crystals are elongate [001] and platy on (010).

Type-locality form

Porous coatings of saucer-shaped aggregates, up to 10 cm2, some consisting of thin plates averaging 15 x 8 x 0.4 um.

Comment

Cell parameters from Steciuk et al. (2023). They differ significantly from the type description which was thought to be triclinic..

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
30ZnZincZinc1165.380719.180
44.35%
8OOxygenOxygen3515.999559.965
34.54%
92UUraniumUranium1238.029238.029
14.68%
20CaCalciumCalcium140.07840.078
2.47%
6CCarbonCarbon312.01136.033
2.22%
1HHydrogenHydrogen281.00828.224
1.74%
Total1621.509100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1989-033
  • Znucaliet

In other languages

German
IMA 1989-033 · Znucalit
Italian
Znucalite

Classification

Strunz
10th ed.

5.ED.45

  • 5CarbonatesClass
  • 5.EUranyl CarbonatesDivision
  • 5.EDUO2:CO3 = 1:3Group
  • 5.ED.45ZnucaliteSpecies
Dana
8th ed.

16b.07.14.01

  • 16bHydrated Carbonates Containing Hydroxyl or HalogenClass
  • 16b.07MiscellaneousType
  • 16b.07.14— unnamed intermediate level —Group
  • 16b.07.14.01ZnucaliteSpecies
CIM

11.11.20

  • 11CarbonatesClass
  • 11.11Carbonates of Cr and UGroup
  • 11.11.20ZnucaliteSpecies

Literature, links & citation

Citations
  1. 1990Ondruš, P., Veselovský, F., Rybka, R. (1990) Znucalite, Zn12(UO2)Ca(CO3)3(OH)22·4H2O, a new mineral from Príbram, Czechoslovakia. Neues Jahrbuch für Mineralogie - Monatshefte, 1990. 393-400
  2. 1991Jambor, John L., Puziewicz, Jacek (1991) New Mineral Names. American Mineralogist, 76 (9-10) 1728-1735
  3. 1993Chiappero, P.J., Sarp, H. (1993) Nouvelles données sur la znucalite et seconde occurrence: Le Mas d'Alary, Lodève (Hérault, France). Archives des Sciences, Genève: 46: 291-301.
  4. 1994Jambor, John L., Grew, Edward S., Roberts, Andrew C. (1994) New Mineral Names. American Mineralogist, 79 (11-12) 1210-1230
  5. 1996Witzke, T. (1996): Znucalit, Zn12(UO2)Ca(CO3)3(OH)22.4H2O, von Bärenhecke bei Glashütte/Sachsen. Der Aufschluss 47 (2), 74-76
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Znucalite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/znucalite-4428},
  note      = {Accessed 2026-05-11}
}