Zubkovaite

Ca3Cu3(AsO4)4
IMA status
  • Approved
IMA symbol
Zub
IMA approved
2018
Also known as
  • IMA2018-008
  • Zubkovaiet

Where it forms, where it's found

Geological setting

a fumarole

Type locality
Arsenatnaya fumarole
  1. Second scoria cone
  2. Northern Breakthrough (North Breach)
  3. Great Fissure eruption (Main Fracture)
  4. Tolbachik Volcanic field
  5. Milkovsky District
  6. Kamchatka Krai
  7. Russia

55.6833°, 160.2333°

1recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Bright sky-blue · turquoise or light bluish-green
Tenacity
brittle
Cleavage
Imperfect/Fair
Density
4.161 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 75°
Refractive index
1.747 – 1.792
Surface relief
High
Principal indices
nα 1.747 · nβ 1.774 · nγ 1.792
Michel-Lévy diagramhighlighted lineδ = 0.0450
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]450 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation450 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2
Cell parameters
a = 16.836(3) Å · b = 5.0405(8) Å · c = 9.117(2) Å
Cell angles
β = 117.39(1) °
Ratio a:b:c
1 : 0.299 : 0.542
Type-locality form

coarse, prismatic crystals, up to 0.01 x 0.01 x 0.2 mm, comprising radiating aggregates or crusts

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
33AsArsenicArsenic474.922299.688
34.58%
8OOxygenOxygen1615.999255.984
29.54%
29CuCopperCopper363.546190.638
22.00%
20CaCalciumCalcium340.078120.234
13.88%
Total866.544100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2018-008
  • Zubkovaiet

In other languages

German
IMA 2018-008 · Zubkovait

Classification

Strunz
10th ed.

8.AC.57

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.APhosphates, etc. without additional anions, without H2ODivision
  • 8.ACWith medium-sized and large cationsGroup
  • 8.AC.57ZubkovaiteSpecies

Literature, links & citation

Citations
  1. 2018Hålenius, U., Hatert, F., Pasero, M., Mills, S. J. (2018) CNMNC Newsletter No 43, New minerals and nomenclature modifications approved in 2018. Mineralogical Magazine, 82 (3) 779-785 doi:10.1180/mgm.2018.72DOI: 10.1180/mgm.2018.72
  2. 2019Pekov, Igor V., Lykova, Inna S., Agakhanov, Atali A., Belakovskiy, Dmitry I., Vigasina, Marina F., Britvin, Sergey N., Turchkova, Anna G., Sidorov, Evgeny G., Scheidl, Katharina S. (2019) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. XII. Zubkovaite, Ca3Cu3(AsO4)4. Mineralogical Magazine, 83 (6) 879-886 doi:10.1180/mgm.2019.33 DOI: 10.1180/mgm.2019.33
  3. 2022(2022) Zubkovaite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Zubkovaite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/zubkovaite-52917},
  note      = {Accessed 2026-05-11}
}