Afmite

Al3(OH)4(H2O)3(PO4)(PO3OH) · H2O
IMA status
  • Approved
IMA symbol
Afm
IMA approved
2010
Also known as
  • Afmiet
  • Afmitt
  • IMA2005-025a

Where it forms, where it's found

Geological setting

In fractures and solution cavities in shale/siltstone. The formation is thought to be largely the result of remobilisation and crystallization during low-temperature hydrothermal activity and/or weathering and ground water activity.

Type locality
Phosphate occurrence
  1. Fumade
  2. Fontrieu
  3. Castres
  4. Tarn
  5. Occitanie
  6. France

43.6583°, 2.4994°

4recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789101.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Colour
Colorless to white · weathering to cream or yellowish
Streak
White
Tenacity
flexible
Cleavage
Perfect

(001) perfect, (010) and (110) good.

Fracture
Irregular/Uneven
Density
2.39 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 70° · 2V calc = 71°
Refractive index
1.554 – 1.566
Surface relief
Moderate
Principal indices
nα 1.554 · nβ 1.558 · nγ 1.566
Pleochroism
Not Visible
UV response
Not fluorescent.
Notes

Y ≈ a; b is at roughly equal angles (~55°) to X and Z.

Michel-Lévy diagramhighlighted lineδ = 0.0120
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]120 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation120 nm
Order1st order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
P-1
Cell parameters
a = 7.386(3) Å · b = 7.716(3) Å · c = 11.345(4) Å
Cell angles
α = 99.773(5) ° · β = 91.141(6) ° · γ = 115.58(5) °
Ratio a:b:c
1 : 1.045 : 1.536
Unit cell volume
571.6 ų
Z
2
Morphology

Tablets on (001).

Twinning

Ubiquitously contact-twinned on (001) and also commonly twinned by rotation on [010] with (010) and (110) composition planes, forming star-like sixlings.

Type-locality form

Cockscomb aggregates of diamond-shaped tablets.

Comment

Cell parameters from from Kampf et al. (2011)

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1615.999255.984
62.13%
13AlAluminiumAluminium326.98280.946
19.65%
15PPhosphorusPhosphorus230.97461.948
15.04%
1HHydrogenHydrogen131.00813.104
3.18%
Total411.982100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Afmiet
  • Afmitt
  • IMA2005-025a

In other languages

German
Afmit · IMA 2005-025a
Italian
afmite

Classification

Strunz
10th ed.

8.DD.15

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DDWith only medium-sized cations, (OH, etc.):RO4= 2:1Group
  • 8.DD.15AfmiteSpecies
Dana
8th ed.

42.09.03.06

  • 42Hydrated Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 42.09(AB)7(XO4)4Zq·xH2OType
  • 42.09.03Turquoise GroupGroup
  • 42.09.03.06AfmiteSpecies

Group, growth & confusion

Often grow together
1 mineral

Literature, links & citation

Citations
  1. 2010Mills, Stuart J., Birch, William D., Kampf, Anthony R., van Wambeke, Leopold (2010) Kobokoboite, Al6(PO4)4(OH)6·11H2O, a new mineral from the Kobokobo pegmatite, Democratic Republic of the Congo. European Journal of Mineralogy, 22 (2) 305-308 doi:10.1127/0935-1221/2010/0022-2014 DOI: 10.1127/0935-1221/2010/0022-2014
  2. 2010Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2010) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) CNMNC Newsletter No 4. Mineralogical Magazine, 74 (4) 797-800 doi:10.1180/s0026461x00038925 DOI: 10.1180/s0026461x00038925
  3. 2011Kampf, Anthony R., Mills, Stuart J., Rossman, George R., Steele, Ian M., Pluth, Joseph J., Favreau, Georges (2011) Afmite, Al3(OH)4(H2O)3(PO4)(PO3OH)·H2O, a new mineral from Fumade, Tarn, France: description and crystal structure. European Journal of Mineralogy, 23 (2) 269-277 doi:10.1127/0935-1221/2011/0023-2093 DOI: 10.1127/0935-1221/2011/0023-2093
  4. 2015(2015) Afmite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Afmite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/afmite-40242},
  note      = {Accessed 2026-05-11}
}