Matulaite

Fe3+Al7(PO4)4(PO3OH)2(OH)8(H2O)8 · 8H2O
IMA status
  • Approved
IMA symbol
Mat
Discovered
1977
IMA approved
1977
Also known as
  • IMA1977-013
  • Matulaiet

Where it forms, where it's found

Geological setting

Oxidized zone of phosphatic iron deposit.

Type locality
Bachman Mine
  1. Hellertown
  2. Lower Saucon Township
  3. Northampton County
  4. Pennsylvania
  5. USA

40.5654°, -75.3310°

12recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789101.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Colorless · white · grayish white
Streak
White
Tenacity
flexible
Cleavage
Perfect

{001)

Fracture
Irregular/Uneven
Density
2.27 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 73°
Refractive index
1.535 – 1.579
Surface relief
Moderate
Principal indices
nα 1.535 · nβ 1.563 · nγ 1.579
Dispersion
very weak
Michel-Lévy diagramhighlighted lineδ = 0.0440
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]440 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation440 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 10.604(2) Å · b = 16.608(4) Å · c = 20.647 Å
Cell angles
β = 98.848(7) °
Ratio a:b:c
1 : 1.566 : 1.947
Z
4
Morphology

Rosettes of pseudohexagonal, thin-tabular, scaly to bladed crystals, to 1 mm, flattened on (001); botyroidal and as spherules.

Type-locality form

Small rosettes of thin tabular crystals and botryoidal forms.

Comment

Space Group: P21/n.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen4815.999767.952
61.89%
13AlAluminiumAluminium726.982188.874
15.22%
15PPhosphorusPhosphorus630.974185.844
14.98%
26FeIronIron155.84555.845
4.50%
1HHydrogenHydrogen421.00842.336
3.41%
Total1240.851100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1977-013
  • Matulaiet

In other languages

German
IMA 1977-013 · Matulait
Italian
Matulaite

Classification

Strunz
10th ed.

8.DK.30

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DKWith large and medium-sized cations, (OH, etc.):RO4 > 1:1 and < 2:1Group
  • 8.DK.30MatulaiteSpecies
Dana
8th ed.

42.13.03.01

  • 42Hydrated Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 42.13MiscellaneousType
  • 42.13.03— unnamed intermediate level —Group
  • 42.13.03.01MatulaiteSpecies
CIM

19.8.17

  • 19PhosphatesClass
  • 19.8Phosphates of Al and other metalsGroup
  • 19.8.17MatulaiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1980Fleischer, M., Cabri, L. J., Chao, G. Y., Pabst, A. (1980) New mineral names. American Mineralogist, 65 (9-10). 1065-1070
  2. 1980Moore, P.B., Ito, J. (1980) Jungit und Matulait: Zwei neue taflige Phosphat-Mineralien [Jungite and matualite: Two new tabular phosphate minerals]. Der Aufschluss , 31 (2) 55-61
  3. 2011Kampf, Anthony R., Mills, Stuart J., Rossman, George R., Steele, Ian M., Pluth, Joseph J., Favreau, Georges (2011) Afmite, Al3(OH)4(H2O)3(PO4)(PO3OH)·H2O, a new mineral from Fumade, Tarn, France: description and crystal structure. European Journal of Mineralogy, 23 (2) 269-277 doi:10.1127/0935-1221/2011/0023-2093 DOI: 10.1127/0935-1221/2011/0023-2093
  4. 2012Kampf, A. R., Mills, S. J., Rumsey, M. S., Spratt, J., Favreau, G. (2012) The crystal structure determination and redefinition of matulaite, Fe3+Al7(PO4)4(PO3OH)2(OH)8(H2O)8·8H2O. Mineralogical Magazine, 76 (3) 517-534 doi:10.1180/minmag.2012.076.3.05 DOI: 10.1180/minmag.2012.076.3.05
  5. 2012Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2012) New minerals and nomenclature modifications approved in 2012. CNMNC Newsletter No 13. Mineralogical Magazine, 76 (3) 807-817 doi:10.1180/minmag.2012.076.3.26 DOI: 10.1180/minmag.2012.076.3.26
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Matulaite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/matulaite-2598},
  note      = {Accessed 2026-05-11}
}