Alumoklyuchevskite

K3Cu2+3AlO2(SO4)4
IMA status
  • Approved
IMA symbol
Akyv
Discovered
1993
IMA approved
1993
Also known as
  • Aluminoklyuchevskit
  • Aluminoklyuchevskita
  • Aluminoklyuchevskite
  • +4 more

Where it forms, where it's found

Geological setting

Deposited by fumarolic gases.

Type locality
Great Fissure eruption (Main Fracture)
  1. Tolbachik Volcanic field
  2. Milkovsky District
  3. Kamchatka Krai
  4. Russia

55.8333°, 160.3333°

5recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102 – 2.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Transparency
Transparent
Colour
dark green
Cleavage
Perfect

{h0l}, perfect

Density
3.001 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 30° · 2V calc = 30°
Refractive index
1.542 – 1.641
Surface relief
Moderate
Principal indices
nα 1.542 · nβ 1.548 · nγ 1.641
Pleochroism
Strong

Z = dark-green, Y = greyish-green, X = dirty-green

Dispersion
weak
Notes

Y = b; X ⊥ b; Y ⊥ b

Michel-Lévy diagramhighlighted lineδ = 0.0990
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]990 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation990 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 4.952(3) Å · b = 11.978(6) Å · c = 14.626(12) Å
Cell angles
α = 87.119(9) ° · β = 80.251(9) ° · γ = 78.070(9) °
Ratio a:b:c
1 : 2.419 : 2.954
Unit cell volume
863.9 ų
Morphology

Long prismatic to needlelike crystals, with equant cross section, elongated parallel [010], to 1 mm; in aggregates.

Type-locality form

Aggregates of prismatic to needle-like crystals, up to 1 mm long and <0.1 mm thick.

Comment

Cell data (above) from Siidra et al. (2017). Originally assumed to be monoclinic, I2, a = 18.772(7), b = 4.967(2), c = 18.468(7) Å, β = 101.66(1)°, V = 1686(1) Å (Krivovichev et al., 2009).

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1815.999287.982
38.34%
29CuCopperCopper363.546190.638
25.38%
16SSulfurSulfur432.060128.240
17.07%
19KPotassiumPotassium339.098117.294
15.62%
13AlAluminiumAluminium126.98226.982
3.59%
Total751.136100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Aluminoklyuchevskit
  • Aluminoklyuchevskita
  • Aluminoklyuchevskite
  • Alumoklyuchevskiet
  • Alumoklyuchevskita
  • Alumoklyuchevskitt
  • IMA1993-004

In other languages

German
Alumoklyuchevskit · IMA 1993-004
Italian
alumoklyuchevskite

Classification

Strunz
10th ed.

7.BC.45

  • 7SulfatesClass
  • 7.BSulfates (selenates, etc.) with additional anions, without H2ODivision
  • 7.BCWith medium-sized and large cationsGroup
  • 7.BC.45AlumoklyuchevskiteSpecies
Dana
8th ed.

28.04.06.02

  • 28Anhydrous Acid and Normal SulfatesClass
  • 28.04MiscellaneousType
  • 28.04.06Klyuchevskite GroupGroup
  • 28.04.06.02AlumoklyuchevskiteSpecies

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1995Gorskaya, M.G., Vergasova, L.P., Filatov, S.K., Rolich, D.V., Ananiev, V.V. (1995) Alumoklyuchevskite, K3Cu3AlO2(SO4)4, a new oxysulfate of K, Cu, and Al from volcanic exhalations, Kamchatka, Russia. Zapiski Vserossijskogo Mineralogicheskogo Obshchestva: 124: 95-100.
  2. 1996Mandarino, Joseph A. (1996) Abstracts of New Mineral Descriptions. The Mineralogical Record, 27 (2) 115-120
  3. 2005(2005) Alumoklyuchevskite. Handbook of Mineralogy. Mineralogical Society of America
  4. 2008Krivovichev, S.V., Filatov, S.K., Cherepansky, P.N. (2008) Crystal structure of alumoklyuchevskite, K3Cu3AlO2(SO4)4. Zapiski Rossiiskogo Mineralogicheskogo Obshchetstva: 137: 114-122 (in Russian).
  5. 2009Krivovichev, S.V., Filatov, S.K., Cherepansky, P.N. (2009) The crystal structure of alumoklyuchevskite, K3Cu3AlO2(SO4)4. Geology of Ore Deposits: 51: 656-662.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Alumoklyuchevskite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/alumoklyuchevskite-6799},
  note      = {Accessed 2026-05-11}
}