Klyuchevskite

K3Cu3Fe3+O2(SO4)4
IMA status
  • Approved
IMA symbol
Kyv
Discovered
1987
IMA approved
1987
Also known as
  • IMA1987-027
  • Klyuchevskiet

Where it forms, where it's found

Geological setting

Fumarole

Type locality
Great Fissure eruption (Main Fracture)
  1. Tolbachik Volcanic field
  2. Milkovsky District
  3. Kamchatka Krai
  4. Russia

55.8333°, 160.3333°

2recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Transparency
Transparent
Colour
Dark green to olive-green
Streak
Pale green
Cleavage
Perfect

On {h0l}

Density
3.00 g/cm³

Optical

Optical type
Biaxial (-) · 2V calc = 11°
Refractive index
1.549 – 1.68
Surface relief
Moderate
Principal indices
nα 1.549 · nβ 1.550 · nγ 1.680
Pleochroism
Visible

X = olive-green, Y = green, Z = dark olive-green

Dispersion
none
Extinction
Parallel extinction
Michel-Lévy diagramhighlighted lineδ = 0.1310
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]1310 nm3rd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation1310 nm
Order3rd order
XPL colour

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 18.405(7) Å · b = 4.94(2) Å · c = 18.667(7) Å
Cell angles
β = 101.5(2) °
Ratio a:b:c
1 : 0.268 : 1.014
Z
4
Type-locality form

Crystals in orientated aggregates, acicular, elongate [010], up to 0.1 mm long and not thicker than 0.01 mm.

Comment

Space Group: I2.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1815.999287.982
36.92%
29CuCopperCopper363.546190.638
24.44%
16SSulfurSulfur432.060128.240
16.44%
19KPotassiumPotassium339.098117.294
15.04%
26FeIronIron155.84555.845
7.16%
Total779.999100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Pb

Synonyms

  • IMA1987-027
  • Klyuchevskiet

In other languages

German
IMA 1987-027 · Klyuchevskit
Italian
Klyuchevskite
Portuguese
IMA1987-027 · Klyuchevskita

Classification

Strunz
10th ed.

7.BC.45

  • 7SulfatesClass
  • 7.BSulfates (selenates, etc.) with additional anions, without H2ODivision
  • 7.BCWith medium-sized and large cationsGroup
  • 7.BC.45KlyuchevskiteSpecies
Dana
8th ed.

30.04.01.01

  • 30Anhydrous Sulfates Containing Hydroxyl or HalogenClass
  • 30.04MiscellaneousType
  • 30.04.01— unnamed intermediate level —Group
  • 30.04.01.01KlyuchevskiteSpecies
CIM

25.2.26

  • 25SulphatesClass
  • 25.2Sulphates of Cu and AgGroup
  • 25.2.26KlyuchevskiteSpecies

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1989Vergasova, L.P., Filatov, S.K., Gorskaya, M.G., Ananiev, V.V., Sharov, A.S. (1989) Klyuchevskite K3Cu3Fe3+O2(SO4)4 — a new mineral from volcanic sublimates. Zapiski Vsesoyuznogo Mineralogicheskogo Obshchestva: 118(1): 70-73.
  2. 1990Jambor, John L.; Puziewicz, Jacek (1990) New Mineral Names. American Mineralogist, 75 (9-10). 1209-1216
  3. 1992Gorskaya, M.G., Filatov, S.K., Rozhdestvenskaya, I.V., Vergasova, L.P. (1992) The crystal structure of klyuchevskite, K3Cu3(Fe,Al)O2(SO4)4, a new mineral from Kamchatka volcanic sublimates. Mineralogical Magazine: 56: 411-416.
  4. 1993Jambor, L., Puziewicz, Jacek (1993) New Mineral Names. American Mineralogist, 78 (3-4) 450-455
  5. 2005(2005) Klyuchevskite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Klyuchevskite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/klyuchevskite-2227},
  note      = {Accessed 2026-05-11}
}