Ammoniovoltaite

(NH4)2Fe2+5Fe3+3Al(SO4)12(H2O)18
IMA status
  • Approved
IMA symbol
Avlt
IMA approved
2017
Also known as
  • Ammoniovoltaiet
  • Ammoniovoltaitt
  • IMA2017-022

Where it forms, where it's found

Geological setting

Geothermal gas/steam vents

Type locality
Severo-Kambalny geothermal field
  1. Kambalny volcanic ridge
  2. Ust-Bolsheretsky District
  3. Kamchatka Krai
  4. Russia

51.4285°, 156.8734°

1recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Opaque
Colour
Black

greenish grey colour in thin fragments

Tenacity
brittle
Cleavage
None Observed
Fracture
Conchoidal

Optical

Optical type
Isotropic
Surface relief
Moderate
Principal indices
n 1.602
Isotropy testPPL ↔ XPL diagnostic
PPL intrinsic colour; no change on stage rotation
XPL extinct at every orientation
Single index
n = 1.602

Crystallography

Crystal system
Isometric
Space group
Fd3c
Cell parameters
a = 27.322(1) Å
Unit cell volume
20396 ų
Z
16
Parting
None
Type-locality form

Euhedral crystals to 50 µm on alunogen

Comment

a = 27.250 at 100 K.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen6615.9991055.934
53.15%
26FeIronIron855.845446.760
22.49%
16SSulfurSulfur1232.060384.720
19.36%
1HHydrogenHydrogen441.00844.352
2.23%
7NNitrogenNitrogen214.00728.014
1.41%
13AlAluminiumAluminium126.98226.982
1.36%
Total1986.762100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Ammoniovoltaiet
  • Ammoniovoltaitt
  • IMA2017-022

In other languages

German
Ammoniovoltait · IMA 2017-022
Italian
Ammoniovoltaite

Classification

Strunz
10th ed.

7.CC

  • 7SulfatesClass
  • 7.CSulfates (selenates, etc.) without additional anions, with H2ODivision
  • 7.CCWith medium-sized and large cationsGroup
  • 7.CCAmmoniovoltaiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 2017Hålenius, U., Hatert, F., Pasero, M., Mills, S. J. (2017) New minerals and nomenclature modifications approved in 2017, CNMNC Newsletter No 38. Mineralogical Magazine, 81 (4) 1033-1038 doi:10.1180/minmag.2017.081.062DOI: 10.1180/minmag.2017.081.062
  2. 2018Zhitova, Elena S., Siidra, Oleg I., Belakovsky, Dmitry I., Shilovskikh, Vladimir V., Nuzhdaev, Anton A., Ismagilova, Rezeda M. (2018) Ammoniovoltaite, (NH4)2Fe2+5Fe3+3Al(SO4)12(H2O)18, a new mineral from the Severo-Kambalny geothermal field, Kamchatka, Russia. Mineralogical Magazine, 82 (5) 1057-1077 doi:10.1180/minmag.2017.081.083 DOI: 10.1180/minmag.2017.081.083
  3. 2020(2020) Ammoniovoltaite. Handbook of Mineralogy. Mineralogical Society of America
  4. 2023Zhitova, Elena S., Sheveleva, Rezeda M., Kupchinenko, Anastasia N., Zolotarev, Andrey A., Pekov, Igor V., Nuzhdaev, Anton A., Davydova, Vesta O., Vlasenko, Natalia S., Plutakhina, Ekaterina Y., Yapaskurt, Vasiliy O., Schweigert, Peter E., Semenova, Tatiana F. (2023) The Crystal Chemistry of Voltaite-Group Minerals from Post-Volcanic and Anthropogenic Occurrences. Symmetry, 15 (12) 2126 doi:10.3390/sym15122126DOI: 10.3390/sym15122126
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Ammoniovoltaite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/ammoniovoltaite-51957},
  note      = {Accessed 2026-05-11}
}