Voltaite

K2Fe2+5Fe3+3Al(SO4)12 · 18H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Vlt
Discovered
1841
Also known as
  • Monsmedite
  • Pettkoite

Where it forms, where it's found

Geological setting

Solfatara

Fumaroles, solfataras, mud volcanoes and as an alteration product of pyrite-rich deposits in arid regions.

Type locality
Solfatara di Pozzuoli
  1. Pozzuoli
  2. Metropolitan City of Naples
  3. Campania
  4. Italy

40.8281°, 14.1417°

123recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103 – 3.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Opaque
Colour
Green to greenish-black · oil-green to pale green in transmitted light.
Streak
Gray-green
Fracture
Conchoidal
Density
2.645 g/cm³

Optical

Surface relief
Moderate
Principal indices
n 1.593 – 1.608
Tropism
Isotropic
Notes

Anomalously biaxial sectors.

Isotropy testPPL ↔ XPL diagnostic
PPL intrinsic colour; no change on stage rotation
XPL extinct at every orientation
Single index
n = 1.601

Crystallography

Crystal system
Isometric
Space group
Fd3c
Cell parameters
a = 27.254(8) Å
Z
16
Morphology

Crystals (to 2 cm) are commonly octahedral and modified by the cube and dodecahedron. Other minor forms are rare. Granular, massive, and in efflorescences.(HoM)

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen6615.9991055.934
52.05%
26FeIronIron855.845446.760
22.02%
16SSulfurSulfur1232.060384.720
18.96%
19KPotassiumPotassium239.09878.196
3.85%
1HHydrogenHydrogen361.00836.288
1.79%
13AlAluminiumAluminium126.98226.982
1.33%
Total2028.880100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Monsmedite
  • Pettkoite

In other languages

French
voltaïte
German
Monsmedit · Pettkoit · Voltait
Spanish
Voltaíta
Italian
Monsmedite · Voltaite
Russian
вольтаит

Classification

Strunz
10th ed.

7.CC.25

  • 7SulfatesClass
  • 7.CSulfates (selenates, etc.) without additional anions, with H2ODivision
  • 7.CCWith medium-sized and large cationsGroup
  • 7.CC.25VoltaiteSpecies
Dana
8th ed.

29.09.01.01

  • 29Hydrated Acid and Normal SulfatesClass
  • 29.09MiscellaneousType
  • 29.09.01Voltaite GroupGroup
  • 29.09.01.01VoltaiteSpecies
CIM

25.11.10

  • 25SulphatesClass
  • 25.11Sulphates of Fe and other metalsGroup
  • 25.11.10VoltaiteSpecies

Group, growth & confusion

Often grow together
1 mineral

Literature, links & citation

Citations
  1. 1792Breislak, S. (1792) Sulfate d' alumine & de fer. in Essais Mineralogiques sur la Solfatare de Pouzzole, Chez Janvier Giaccio (Naples): 148-158 (155).
  2. 1840Memorie Mineralogische e Geologiche - Napoli (1840) 17.
  3. 1841Scacchi (1841): 17.
  4. 1841Scacchi, A. (1841) Della Voltaite, nouva specie di minerale trovata nella solfatara di Pozzuoli. 1, in Antologia di Scienze Naturali, R. Piria (Napoli): 67-71.
  5. 1843Scacchi (1843) Journal für praktische Chemie, Leipzig: 28: 487.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Voltaite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/voltaite-4203},
  note      = {Accessed 2026-05-11}
}