Anorpiment

As2S3
IMA status
  • Approved
IMA symbol
Apm
IMA approved
2011
Also known as
  • IMA2011-014

Where it forms, where it's found

Type locality
Palomo mines
  1. Santa Ana District
  2. Castrovirreyna Province
  3. Huancavelica
  4. Peru

-13.0940°, -75.0549°

2recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789101.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Greenish yellow
Streak
Yellow
Tenacity
sectile
Cleavage
Perfect

Perfect and easy on (001)

Fracture
Irregular/Uneven
Density
3.33 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 35 – 40°
Notes

All indices of refraction are greater than 2.

Crystallography

Crystal system
Triclinic
Space group
P-1
Cell parameters
a = 5.7577(2) Å · b = 8.7169(3) Å · c = 10.2682(7) Å
Cell angles
α = 78.152(7) ° · β = 75.817(7) ° · γ = 89.861(6) °
Ratio a:b:c
1 : 1.514 : 1.783
Unit cell volume
488.38 ų
Z
4
Morphology

The crystal forms include (010), (110), (110), (001), (021) and (021). The faces of the (110) and (110) forms are typically incompletely formed and cavernous.

Type-locality form

Drusy coatings of wedge shaped crystals up to 0.2 mm.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
33AsArsenicArsenic274.922149.844
60.91%
16SSulfurSulfur332.06096.180
39.09%
Total246.024100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2011-014

In other languages

German
Anauripigment · IMA 2011-014
Italian
anorpiment

Classification

Strunz
10th ed.

2.FA

  • 2Sulfides and SulfosaltsClass
  • 2.FSulfides of arsenic, alkalies; sulfides with halide, oxide, hydroxide, H2ODivision
  • 2.FAWith As, (Sb), SGroup
  • 2.FAAnorpimentSpecies

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 2011Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2011) New minerals and nomenclature modifications approved in 2011, CNMNC Newsletter No. 10. Mineralogical Magazine, 75 (5) 2549-2561 doi:10.1180/minmag.2011.075.5.2549 DOI: 10.1180/minmag.2011.075.5.2549
  2. 2011Kampf, A. R., Downs, R. T., Housley, R. M., Jenkins, R. A., Hyršl, J. (2011) Anorpiment, As2S3, the triclinic dimorph of orpiment. Mineralogical Magazine, 75 (6) 2857-2867 doi:10.1180/minmag.2011.075.6.2857DOI: 10.1180/minmag.2011.075.6.2857
  3. 2013(2013) Anorpiment. Handbook of Mineralogy. Mineralogical Society of America
  4. 2023Banaru, D. A., Aksenov, S. M., Yamnova, N. A., Banaru, A. M. (2023) Structural Complexity of Molecular, Chain, and Layered Crystal Structures of Natural and Synthetic Arsenic Sulfides. Crystallography Reports, 68 (2). 223-236 doi:10.1134/s1063774523020037DOI: 10.1134/s1063774523020037
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Anorpiment — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/anorpiment-42349},
  note      = {Accessed 2026-05-11}
}