Arcanite

K2(SO4)
IMA status
  • Approved
  • Grandfathered
IMA symbol
Acn
Discovered
1845
Also known as
  • Arcaniet
  • Arcanitt
  • Arkanita
  • +5 more

Where it forms, where it's found

Geological setting

Not applicable.

Type locality
Santa Ana Mine
  1. Trabuco Canyon
  2. Trabuco Canyon [town]
  3. Orange County
  4. California
  5. USA
31recorded occurrences
Source · OpenStreetMap

Varieties

Physical

Hardness
123456789102/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Colourless · white · yellow
Cleavage
Distinct/Good

On (010) and (001).

Density
2.663 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 67° · 2V calc = 70°
Refractive index
1.4935 – 1.4973
Surface relief
Low
Principal indices
nα 1.4935 · nβ 1.4947 · nγ 1.4973
Dispersion
r > v strong
Michel-Lévy diagramhighlighted lineδ = 0.0038
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]38 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation38 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Cell parameters
a = 5.77 Å · b = 10.07 Å · c = 7.48 Å
Ratio a:b:c
1 : 1.745 : 1.296
Z
4
Morphology

Thin tablets comprised of sixling cyclic twins bounded by (001), (011), and (112) (Santa Ana Mine). Artificial crystals frequently twinned.

Twinning

On (110), cyclic at times; pseudo-hexagonal groupings.

Type-locality form

Thin tablets in wood.

Comment

Space Group: P nam (synthetic)

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
19KPotassiumPotassium239.09878.196
44.87%
8OOxygenOxygen415.99963.996
36.73%
16SSulfurSulfur132.06032.060
18.40%
Total174.252100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Arcaniet
  • Arcanitt
  • Arkanita
  • Arkanite
  • Kalisulphat
  • Potasse sulfatée
  • Schwefelsaures Kali
  • Sulfate of Potash

In other languages

French
Arcanite
German
Aphthalose · Arcanit · Arcanum duplicatum · Arkanit · Schwefelsaures Kali
Italian
Arcanite

Classification

Strunz
10th ed.

7.AD.05

  • 7SulfatesClass
  • 7.ASulfates (selenates, etc.) without additional anions, without H2ODivision
  • 7.ADWith only large cationsGroup
  • 7.AD.05ArcaniteSpecies
Dana
8th ed.

28.02.01.02

  • 28Anhydrous Acid and Normal SulfatesClass
  • 28.02A2XO4Type
  • 28.02.01— unnamed intermediate level —Group
  • 28.02.01.02ArcaniteSpecies
CIM

25.1.4

  • 25SulphatesClass
  • 25.1Sulphates of the alkali metals and ammoniumGroup
  • 25.1.4ArcaniteSpecies

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1845Haidinger, W. (1845) Erste Klasse: Akrogenide. IV. Ordnung. Salze. XIII. Pikrochylinsalz. Arcanit. in: Handbuch der bestimmenden Mineralogie, Vienna, 487-492.
  2. 1895Tutton (1895) Zeitschrift für Kristallographie, Mineralogie und Petrographie, Leipzig: 24: 5.
  3. 1908Eakle (1908) Bulletin of the Department of Geology, University of California: 5: 232.
  4. 1928Ogg (1928) Philosophical Magazine and Journal of Science: 5: 354.
  5. 1950Frondel, Clifford (1950) Notes and news: Notes on arcanite, ammonian aphthitalite and oxammite. American Mineralogist, 35 (7-8) 596-598
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Arcanite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/arcanite-314},
  note      = {Accessed 2026-05-11}
}