Mascagnite

(NH4)2(SO4)
IMA status
  • Approved
  • Grandfathered
IMA symbol
Msc
Discovered
1800
Also known as
  • Alkali volatil vitriolé
  • Ammoniaque sulfatée
  • Mascagniet
  • +7 more

Where it forms, where it's found

Geological setting

Sublimation product from fumeroles, solfataras, burning coal seams.

Type locality
Travale
  1. Montieri
  2. Grosseto Province
  3. Tuscany
  4. Italy

43.1675°, 11.0080°

63recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102 – 2.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous · dull
Transparency
Transparent · Translucent · Opaque
Colour
Colourless · grey · yellowish-grey · yellow · colourless in transmitted light
Tenacity
sectile
Cleavage
Distinct/Good

On (001).

Fracture
Irregular/Uneven
Density
1.768 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 52° · 2V calc = 58°
Refractive index
1.52 – 1.533
Surface relief
Moderate
Principal indices
nα 1.52 · nβ 1.523 · nγ 1.533
Dispersion
relatively strong r > v
Michel-Lévy diagramhighlighted lineδ = 0.0130
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]130 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation130 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
#71
Cell parameters
a = 7.782 Å · b = 5.993 Å · c = 10.636 Å
Ratio a:b:c
1 : 0.770 : 1.367
Z
4
Morphology

Well-formed natural crystals are rare. Mealy crusts and stalactitic forms. Artificial crystals equant to short prismatic [001], frequently flattened (010); also prismatic [100]; also flattened (100), rare.

Twinning

On (101) common, often repeated yielding a pseudo-hexagonal habit; also polysynthetic.

Parting
Twin gliding with K1(110), K2(13_0).
Comment

Synthetic

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen415.99963.996
48.43%
16SSulfurSulfur132.06032.060
24.27%
7NNitrogenNitrogen214.00728.014
21.20%
1HHydrogenHydrogen81.0088.064
6.10%
Total132.134100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Alkali volatil vitriolé
  • Ammoniaque sulfatée
  • Mascagniet
  • Mascagnine
  • Mascagnit
  • Sal ammoniacum secretum Glauberi
  • Sale ammoniacale composto d'acido sulfureo
  • Schwefelsaures Ammoniak
  • Sel ammoniac vitriolique
  • Sulfate of Ammonia

In other languages

French
mascagnite
German
Mascagnin · Mascagnit
Italian
Mascagnite

Classification

Strunz
10th ed.

7.AD.05

  • 7SulfatesClass
  • 7.ASulfates (selenates, etc.) without additional anions, without H2ODivision
  • 7.ADWith only large cationsGroup
  • 7.AD.05MascagniteSpecies
Dana
8th ed.

28.02.01.01

  • 28Anhydrous Acid and Normal SulfatesClass
  • 28.02A2XO4Type
  • 28.02.01— unnamed intermediate level —Group
  • 28.02.01.01MascagniteSpecies
CIM

25.1.8

  • 25SulphatesClass
  • 25.1Sulphates of the alkali metals and ammoniumGroup
  • 25.1.8MascagniteSpecies

Group, growth & confusion

Often grow together
1 mineral
Commonly confused with
2 minerals

Literature, links & citation

Citations
  1. 1777Sage, B.G. (1777) Eléméns de minéralogie docimastique, second edition, 2 volumes: 1: 62 (as Sel ammoniac vitriolique).
  2. 1779Mascagni (1779) Dei Lagoni del Senese..., Sienna: 36 (as Sale ammoniacale composto d'acido sulfureo)
  3. 1800Karsten, D.L.G. (1800) Mineralogische Tabellen, Berlin. First edition: 40, 75 (as Maskagnin).
  4. 1822Haüy, René Just (1822) Traité de Minéralogie (2nd ed.) Vol. 2. Bachelier, Paris.
  5. 1830Mitscherlich (1830) Annalen der Physik, Halle, Leipzig: 18: 169 (artificial crystals).
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Mascagnite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/mascagnite-2584},
  note      = {Accessed 2026-05-11}
}