Where it forms, where it's found
- Geological setting
Sublimation product from fumeroles, solfataras, burning coal seams.
- Type locality
- Travale
- Montieri
- Grosseto Province
- Tuscany
- Italy
43.1675°, 11.0080°
Physical
- Hardness
- 1Talc
- 2Gypsum
- 3Calcite
- 4Fluorite
- 5Apatite
- 6Orthoclase
- 7Quartz
- 8Topaz
- 9Corundum
- 10Diamond
- Lustre
- Vitreous · dull
- Transparency
- Transparent · Translucent · Opaque
- Colour
- Colourless · grey · yellowish-grey · yellow · colourless in transmitted light
- Tenacity
- sectile
- Cleavage
- Distinct/Good
On (001).
- Fracture
- Irregular/Uneven
- Density
- 1.768 g/cm³
Optical
- Optical type
- Biaxial (+) · 2V measured = 52° · 2V calc = 58°
- Refractive index
- 1.52 – 1.533
- Surface relief
- Moderate
- Principal indices
- nα 1.52 · nβ 1.523 · nγ 1.533
- Dispersion
- relatively strong r > v
Crystallography
- Space group
- #71
- Cell parameters
- a = 7.782 Å · b = 5.993 Å · c = 10.636 Å
- Ratio a:b:c
- 1 : 0.770 : 1.367
- Z
- 4
- Morphology
Well-formed natural crystals are rare. Mealy crusts and stalactitic forms. Artificial crystals equant to short prismatic [001], frequently flattened (010); also prismatic [100]; also flattened (100), rare.
- Twinning
On (101) common, often repeated yielding a pseudo-hexagonal habit; also polysynthetic.
- Parting
- Twin gliding with K1(110), K2(13_0).
- Comment
Synthetic
Chemical composition
Synonyms
- Alkali volatil vitriolé
- Ammoniaque sulfatée
- Mascagniet
- Mascagnine
- Mascagnit
- Sal ammoniacum secretum Glauberi
- Sale ammoniacale composto d'acido sulfureo
- Schwefelsaures Ammoniak
- Sel ammoniac vitriolique
- Sulfate of Ammonia
In other languages
- French
- mascagnite
- German
- Mascagnin · Mascagnit
- Italian
- Mascagnite
Classification
7.AD.05
- 7SulfatesClass
- 7.ASulfates (selenates, etc.) without additional anions, without H2ODivision
- 7.ADWith only large cationsGroup
- 7.AD.05MascagniteSpecies
28.02.01.01
- 28Anhydrous Acid and Normal SulfatesClass
- 28.02A2XO4Type
- 28.02.01— unnamed intermediate level —Group
- 28.02.01.01MascagniteSpecies
25.1.8
- 25SulphatesClass
- 25.1Sulphates of the alkali metals and ammoniumGroup
- 25.1.8MascagniteSpecies
Group, growth & confusion
Literature, links & citation
- 1777Sage, B.G. (1777) Eléméns de minéralogie docimastique, second edition, 2 volumes: 1: 62 (as Sel ammoniac vitriolique).
- 1779Mascagni (1779) Dei Lagoni del Senese..., Sienna: 36 (as Sale ammoniacale composto d'acido sulfureo)
- 1800Karsten, D.L.G. (1800) Mineralogische Tabellen, Berlin. First edition: 40, 75 (as Maskagnin).
- 1822Haüy, René Just (1822) Traité de Minéralogie (2nd ed.) Vol. 2. Bachelier, Paris.
- 1830Mitscherlich (1830) Annalen der Physik, Halle, Leipzig: 18: 169 (artificial crystals).
@misc{mineral2026,
author = {Mineral Index editorial board},
title = {Mascagnite — Mineral Index},
year = {2026},
url = {https://mineralindex.org/minerals/mascagnite-2584},
note = {Accessed 2026-05-11}
}