Archerite

H2K(PO4)
IMA status
  • Approved
IMA symbol
Aht
Discovered
1977
Also known as
  • Archeriet
  • Archeritt
  • IMA1975-008

Where it forms, where it's found

Geological setting

Guano deposit.

Guano deposits

Type locality
Petrogale Cave
  1. Madura Roadhouse
  2. Dundas Shire
  3. Western Australia
  4. Australia

-31.8693°, 127.3887°

7recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789101 – 2/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
White
Streak
White
Tenacity
brittle
Cleavage
None Observed
Fracture
Irregular/Uneven
Density
2.23 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.468 – 1.513
Surface relief
Low
Principal indices
nω 1.511 – 1.513 · nε 1.468 – 1.470
Birefringence
0.041
Extinction
parallel
Michel-Lévy diagramhighlighted lineδ = 0.0410
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]410 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation410 nm
Order1st order
XPL colour

Crystallography

Crystal system
Tetragonal
Space group
I-4 2d
Cell parameters
a = 7.451 Å · c = 6.974 Å
Z
4
Morphology

Prismatic crystals with pyramids.

Type-locality form

Stalactites and wall and floor crusts. Crystals up to 2 mm in length.

Comment

Ranges a 7.453, b 6.972

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen415.99963.996
47.03%
19KPotassiumPotassium139.09839.098
28.73%
15PPhosphorusPhosphorus130.97430.974
22.76%
1HHydrogenHydrogen21.0082.016
1.48%
Total136.084100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Archeriet
  • Archeritt
  • IMA1975-008

In other languages

French
archerite
German
Archerit · IMA 1975-008
Italian
Archerite
Chinese
磷钾石

Classification

Strunz
10th ed.

8.AD.15

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.APhosphates, etc. without additional anions, without H2ODivision
  • 8.ADWith only large cationsGroup
  • 8.AD.15ArcheriteSpecies
Dana
8th ed.

37.01.04.02

  • 37Anhydrous Acid Phosphates, Arsenates and VanadatesClass
  • 37.01MiscellaneousType
  • 37.01.04— unnamed intermediate level —Group
  • 37.01.04.02ArcheriteSpecies
CIM

19.1.7

  • 19PhosphatesClass
  • 19.1Phosphates of the alkali metalsGroup
  • 19.1.7ArcheriteSpecies

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1930West, J. (1930) XXVI. a quantitative X-ray analysis of the structure of potassium dihydrogen phosphate (KH2PO4). Zeitschrift für Kristallographie: 74 : 306-332.
  2. 1952Frazer, B.C., Pepinsky, R. (1952) Structural changes in the ferroelectric transition of KH2PO4. Physical Review: 85: 479-480.
  3. 1953Frazer, B.C., Pepinsky, R. (1953) X-ray analysis of the ferroelectric transition in KH2PO4. Acta Crystallographica: 6: 273-285.
  4. 1977Fleischer, Michael, Pabst, Adolf, Mandarino, J. A., Chao, George Y. (1977) New mineral names. American Mineralogist, 62 (9-10) 1057-1061
  5. 1977Bridge, P. J. (1977) Archerite, (K,NH4)H2PO4, a new mineral from Madura, Western Australia. Mineralogical Magazine, 41 (317) 33-35 doi:10.1180/minmag.1977.041.317.05 DOI: 10.1180/minmag.1977.041.317.05
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Archerite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/archerite-315},
  note      = {Accessed 2026-05-11}
}