Biphosphammite

(NH4)H2(PO4)
IMA status
  • Approved
  • Grandfathered
IMA symbol
Bpam
Discovered
1870
Also known as
  • Biphosphammiet
  • Biphosphammita

Where it forms, where it's found

Geological setting

Guano deposits

Guano caves

Type locality
Murra-El-Elevyn Cave
  1. Cocklebiddy Roadhouse
  2. Dundas Shire
  3. Western Australia
  4. Australia

-32.0433°, 126.0386°

13recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789101 – 2/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
White · pale yellow or colorless · colorless in transmitted light.
Streak
White
Tenacity
brittle
Cleavage
None Observed
Fracture
Irregular/Uneven
Density
2.04 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.48 – 1.525
Surface relief
Moderate
Principal indices
nω 1.525 · nε 1.48
Birefringence
0.045
Pleochroism
Non-pleochroic
Extinction
parallel
Michel-Lévy diagramhighlighted lineδ = 0.0450
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]450 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation450 nm
Order1st order
XPL colour

Crystallography

Crystal system
Tetragonal
Space group
I41 2 2
Cell parameters
a = 7.494 Å · c = 7.340 Å
Z
4
Morphology

Fine-grained granular crust.

Type-locality form

White, powdery effluorescence

Comment

AC B 29:2721 (1973); Also a 7.502, c 7.554

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen415.99963.996
55.63%
15PPhosphorusPhosphorus130.97430.974
26.93%
7NNitrogenNitrogen114.00714.007
12.18%
1HHydrogenHydrogen61.0086.048
5.26%
Total115.025100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Biphosphammiet
  • Biphosphammita

In other languages

German
Biphosphammit
Italian
Bifosfammite · Biphosphammite

Classification

Strunz
10th ed.

8.AD.15

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.APhosphates, etc. without additional anions, without H2ODivision
  • 8.ADWith only large cationsGroup
  • 8.AD.15BiphosphammiteSpecies
Dana
8th ed.

37.01.04.01

  • 37Anhydrous Acid Phosphates, Arsenates and VanadatesClass
  • 37.01MiscellaneousType
  • 37.01.04— unnamed intermediate level —Group
  • 37.01.04.01BiphosphammiteSpecies
CIM

19.1.8

  • 19PhosphatesClass
  • 19.1Phosphates of the alkali metalsGroup
  • 19.1.8BiphosphammiteSpecies

Group, growth & confusion

Often grow together
3 minerals
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1870Shepard, C.U. (1870) Notice of the Guanape Island guano. The Rural Carolinian: 1: 469-471.
  2. 1972Pryce, M. W. (1972) Biphosphammite: a second occurrence. Mineralogical Magazine, 38 (300) 965-967 doi:10.1180/minmag.1972.038.300.08 DOI: 10.1180/minmag.1972.038.300.08
  3. 1973Fleischer, M. (1973) New mineral names. American Mineralogist, 58 (7-8). 805-807
  4. 1973Khan, A. A., Baur, W. H. (1973) Refinement of the crystal structures of ammonium dihydrogen phosphate and ammonium dihydrogen arsenate. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, 29 (12) 2721-2726 doi:10.1107/s0567740873007442DOI: 10.1107/s0567740873007442
  5. 2005(2005) Biphosphammite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Biphosphammite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/biphosphammite-678},
  note      = {Accessed 2026-05-11}
}