Asagiite

NiCu4(SO4)2(OH)6 · 6H2O
IMA status
  • Approved
IMA symbol
Asa
Also known as
  • Asagiiet
  • Asagïite
  • Asagiitt
  • +2 more

Where it forms, where it's found

Geological setting

Secondary mineral of fractures in a serpentinite.

Type locality
Nakauri mine
  1. Shinshiro city
  2. Aichi Prefecture
  3. Japan

34.8494°, 137.5521°

7recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Pale blue-green (unique enough to impart its name)
Streak
White
Tenacity
brittle
Cleavage
Perfect

on (001)

Density
2.90 g/cm³

Optical

Optical type
Biaxial (-) · 2V calc = 52.4°
Refractive index
1.577 – 1.631
Surface relief
Moderate
Principal indices
nα 1.577 · nβ 1.620 · nγ 1.631
UV response
non-fluorescent
Michel-Lévy diagramhighlighted lineδ = 0.0540
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]540 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation540 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/c
Cell parameters
a = 5.6095(8) Å · b = 6.1259(7) Å · c = 23.758(3) Å
Cell angles
β = 95.288(4) °
Ratio a:b:c
1 : 1.092 : 4.235
Type-locality form

Thin plate-like crystals (typically 0.1-0.2 mm, rarely up to 0.5 mm in length), growing on smithsonite aggregates.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2015.999319.980
44.74%
29CuCopperCopper463.546254.184
35.54%
16SSulfurSulfur232.06064.120
8.97%
28NiNickelNickel158.69358.693
8.21%
1HHydrogenHydrogen181.00818.144
2.54%
Total715.121100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Asagiiet
  • Asagïite
  • Asagiitt
  • Asaguiita
  • IMA2022-065

In other languages

German
Asagiit
Japanese
浅葱石

Classification

Strunz
10th ed.

7.DD

  • 7SulfatesClass
  • 7.DSulfates (selenates, etc.) with additional anions, with H2ODivision
  • 7.DDWith only medium-sized cations; sheets of edge-sharing octahedraGroup
  • 7.DDAsagiiteSpecies

Group, growth & confusion

In the same group
3 members

Literature, links & citation

Citations
  1. 2022Miyawaki, Ritsuro, Hatert, Frédéric, Pasero, Marco, Mills, Stuart J. (2022) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) – Newsletter 70. European Journal of Mineralogy, 34 (6) 591-601 doi:10.5194/ejm-34-591-2022 DOI: 10.5194/ejm-34-591-2022
  2. 2023Nishio-Hamane, Daisuke, Yajima, Takeshi, Shimobayashi, Norimasa, Ohnishi, Masayuki, Niwa, Takefumi (2023) Asagiite, NiCu4(SO4)2(OH)6·6H2O, a new member of the ktenasite group from the Nakauri mine, Shinshiro City, Aichi Prefecture, Japan. Journal of Mineralogical and Petrological Sciences, 118 (1). 230711 doi:10.2465/jmps.230711 DOI: 10.2465/jmps.230711
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Asagiite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/asagiite-470431},
  note      = {Accessed 2026-05-11}
}