Atheneite

Pd2(As0.75Hg0.25)
IMA status
  • Approved
IMA symbol
Ah
Discovered
1974
Also known as
  • Atheneiet
  • Atheneitt
  • IMA1973-050

Where it forms, where it's found

Geological setting

Placer

Type locality
Itabira
  1. Minas Gerais
  2. Brazil
17recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789105/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Metallic
Transparency
Opaque
Colour
Grey
Density
10.2 g/cm³

Optical

Pleochroism
Weak

Pale yellow-white to bluish gray-white

Optical colour
White with a bluish tint
Anisotropism
Distinct
Tropism
Anisotropic
Reflectance R%
(46.1, 48.3) 400, (47.4, 49.8) 420, (48.5, 50.9) 440, (49.7, 52.4) 460, (50.8, 53.6) 480, (51.9, 54.8) 500, (53.0, 55.8) 520, (54.0, 56.7) 540, (54.8, 57.3) 560, (55.7, 57.8) 580, (56.4, 58.3) 600, (57.0, 58.5) 620, (57.4, 58.6) 640, (57.6, 58.7) 660, (57.9, 59.0) 680, (58.2, 59.1) 700
Reflected-light panel
53.5 %anisotropic · dual curve
Specimen sRGB 255, 180, 94
White reference100 % reflector under same lamp
R₁ R₂
Mode
Anisotropism
Distinct
Reflected colour
White with a bluish tint

Crystallography

Crystal system
Hexagonal
Space group
P-62m
Cell parameters
a = 6.813 Å · c = 3.4892 Å
Z
3
Morphology

Blebs

Comment

The refinement of an anisotropic model led to an R index of 7.26% for 261 independent reflections

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
46PdPalladiumPalladium2106.420212.840
66.68%
33AsArsenicArsenic0.7574.92256.191
17.61%
80HgMercuryMercury0.25200.59250.148
15.71%
Total319.180100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Au
  • Cu
  • Sb

Synonyms

  • Atheneiet
  • Atheneitt
  • IMA1973-050

In other languages

German
Atheneit · Atheneite · IMA 1973-050
Italian
ateneite · atheneite

Classification

Strunz
10th ed.

2.AC.05a

  • 2Sulfides and SulfosaltsClass
  • 2.AAlloysDivision
  • 2.ACAlloys of metalloids with PGEGroup
  • 2.AC.05aAtheneiteSpecies
Dana
8th ed.

02.02.04.01

  • 02SulfidesClass
  • 02.02AmBnXp, with (m+n):p = 3:1Type
  • 02.02.04— unnamed intermediate level —Group
  • 02.02.04.01AtheneiteSpecies
CIM

3.12.26

  • 3Sulphides, Selenides, Tellurides, Arsenides and Bismuthides (except the arsenides, antimonides and bismuthides of Cu, Ag and Au, which are included in Section 1)Class
  • 3.12Sulphides etc. of the platinum metalsGroup
  • 3.12.26AtheneiteSpecies

Group, growth & confusion

Often grow together
2 minerals

Literature, links & citation

Citations
  1. 1974Fleischer, Michael (1974) New mineral names. American Mineralogist, 59 (11-12). 1330-1332
  2. 1974Clark, A. M., Criddle, A. J., Fejer, E. E. (1974) Palladium arsenide-antimonides from Itabira, Minas Gerais, Brazil. Mineralogical Magazine, 39 (305). 528-543 doi:10.1180/minmag.1974.039.305.05 DOI: 10.1180/minmag.1974.039.305.05
  3. 2002Cabral, A. R., Lehmann, B., Kwitko-Ribeiro, R., Costa, C. H. C. (2002) Palladium and platinum minerals from the Serra Pelada Au-Pd-Pt deposit, Carajas mineral province, northern Brazil. The Canadian Mineralogist, 40 (5) 1451-1463 doi:10.2113/gscanmin.40.5.1451 DOI: 10.2113/gscanmin.40.5.1451
  4. 2005(2005) Atheneite. Handbook of Mineralogy. Mineralogical Society of America
  5. 2010Bindi, L. (2010) Atheneite, [Pd2][As0.75Hg0.25], from Itabira, Minas Gerais, Brazil: crystal structure and revision of the chemical formula. The Canadian Mineralogist, 48 (5) 1149-1155 doi:10.3749/canmin.48.5.1149 DOI: 10.3749/canmin.48.5.1149
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Atheneite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/atheneite-409},
  note      = {Accessed 2026-05-11}
}