Bararite

(NH4)2SiF6
IMA status
  • Approved
  • Grandfathered
IMA symbol
Brr
Discovered
1951
Also known as
  • Barariet

Where it forms, where it's found

Geological setting

Above a burning coal seam.

Above burning coal seams; sublimation product at fumaroles and in burning anthracite piles.

Type locality
Barari Colliery
  1. Jharia Coalfield
  2. Dhanbad District
  3. Jharkhand
  4. India

23.7000°, 86.4278°

7recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Transparency
Transparent
Colour
White · colourless in thin section
Streak
White
Cleavage
Perfect

on (0001)

Density
2.152 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.391 – 1.406
Surface relief
Low
Principal indices
nω 1.406 · nε 1.391
Michel-Lévy diagramhighlighted lineδ = 0.0150
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]150 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation150 nm
Order1st order
XPL colour

Crystallography

Crystal system
Trigonal
Cell parameters
a = 5.77 Å · c = 4.78 Å
Z
1
Morphology

Minute crystals, flattened on (0001), may be elongated perpendicular to [0001]; also arborescent and mammillary. Commonly included within cryptohalite.

Twinning

Dartlike or paddlewheel twins, with twin plane inclined to (0001)

Type-locality form

Arborescent, mammillary; commonly included within cryptohalite.

Comment

Space Group: C_3m - synthetic

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
9FFluorineFluorine618.998113.988
63.98%
14SiSiliconSilicon128.08528.085
15.76%
7NNitrogenNitrogen214.00728.014
15.73%
1HHydrogenHydrogen81.0088.064
4.53%
Total178.151100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Barariet

In other languages

French
bararite
German
Bararit
Spanish
Bararita
Italian
Bararite
Chinese
氟硅铵石
Traditional Chinese
氟矽铵石
Russian
Барарит

Classification

Strunz
10th ed.

3.CH.10

  • 3HalidesClass
  • 3.CComplex halidesDivision
  • 3.CHSilicofluoridesGroup
  • 3.CH.10BarariteSpecies
Dana
8th ed.

11.05.02.02

  • 11Halide ComplexesClass
  • 11.05AmBX6Type
  • 11.05.02Malladrite GroupGroup
  • 11.05.02.02BarariteSpecies
CIM

8.12.6

  • 8Halides - Fluorides, Chlorides, Bromides and Iodides; also Fluoborates and FluosilicatesClass
  • 8.12— unnamed intermediate level —Group
  • 8.12.6BarariteSpecies

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1873Scacchi, A. (1873) Contribuzioni mineralogiche per servire alla storia dell’ incendio Vesuviano del Mese di Aprile, 1872. Part 2. Reale Accademia delle Scienze Fisische e Matematiche (Naples): 1–69.
  2. 1874Scacchi, A. (1874) Appendice alle contribuzioni mineralogiche sull’ incendio vesuviano del 1872. Rendiconto dell’Accademia delle scienze fisiche e matematiche (sezione della Società reale di Napoli): 8: 179–180.
  3. 1903Gossner, B. (1903) Ammoniumsiliciumfluorid. Zeitschrift für Kristallographie, Mineralogie und Petrographie, Leipzig: 38: 147-148.
  4. 1926Christie, W.A.K. (1926) An Occurrence of Cryptohalite (Ammonium Fluosilicate). Records of the Geological Survey of India, Calcutta: 59: 233.
  5. 1934Goßner, B.; Kraus, O. (1934) Das Kristallgitter von Ammoniumhexafluorosilikat (NH4)2SiF6. Zeitschrift für Kristallographie, Mineralogie und Petrographie, 88 (1-6). 223-225 doi:10.1524/zkri.1934.88.1.223 DOI: 10.1524/zkri.1934.88.1.223
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Bararite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/bararite-511},
  note      = {Accessed 2026-05-11}
}