Cryptohalite

(NH4)2SiF6
IMA status
  • Approved
  • Grandfathered
IMA symbol
Cphl
Discovered
1873
Also known as
  • Criptoalite
  • Cryptohaliet

Where it forms, where it's found

Type locality
Mount Vesuvius
  1. Metropolitan City of Naples
  2. Campania
  3. Italy
15recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Colour
Colourless · white · grey · colourless in transmitted light
Cleavage
Perfect

on (111)

Density
2.004 g/cm³

Optical

Optical type
Isotropic
Isotropy testPPL ↔ XPL diagnostic
PPL intrinsic colour; no change on stage rotation
XPL extinct at every orientation

Crystallography

Crystal system
Isometric
Space group
#224
Cell parameters
a = 8.39 Å
Morphology

Artificial crystals are cubo-octahedral and octahedral. Massive, as lumps with a mammillary surface or crusts; arborescent.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
9FFluorineFluorine618.998113.988
63.98%
14SiSiliconSilicon128.08528.085
15.76%
7NNitrogenNitrogen214.00728.014
15.73%
1HHydrogenHydrogen81.0088.064
4.53%
Total178.151100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Criptoalite
  • Cryptohaliet

In other languages

German
Kryptohalit
Italian
Criptohalite · Cryptohalite
Chinese
方氟硅铵石

Classification

Strunz
10th ed.

3.CH.15

  • 3HalidesClass
  • 3.CComplex halidesDivision
  • 3.CHSilicofluoridesGroup
  • 3.CH.15CryptohaliteSpecies
Dana
8th ed.

11.05.01.02

  • 11Halide ComplexesClass
  • 11.05AmBX6Type
  • 11.05.01— unnamed intermediate level —Group
  • 11.05.01.02CryptohaliteSpecies
CIM

8.12.5

  • 8Halides - Fluorides, Chlorides, Bromides and Iodides; also Fluoborates and FluosilicatesClass
  • 8.12— unnamed intermediate level —Group
  • 8.12.5CryptohaliteSpecies

Group, growth & confusion

Commonly confused with
2 minerals

Literature, links & citation

Citations
  1. 1873Scacchi, A. (1873) Contribuzioni mineralogiche per servire alla storia dell’ incendio Vesuviano del Mese di Aprile, 1872. Part 2. Reale Accademia delle Scienze Fisische e Matematiche (Naples): 1–69. (as Criptoalite).
  2. 1874Topsøe, H., Christiansen, C. (1874) Recherches optique sur quelques series de substances isomorphes. Annales de chimie et de physique, Paris: 1: 5-99 (22-23).
  3. 1903Gossner, B. (1903) Ammoniumsiliciumfluorid. Zeitschrift für Kristallographie, Mineralogie und Petrographie, Leipzig: 38: 147-148.
  4. 1922Bozorth, R.M. (1922) The crystal structure of ammonium fluosilicate. Journal of the American Chemical Society: 44(5): 1066-1070.
  5. 1926Christie, W.A.K. (1926) An Occurrence of Cryptohalite (Ammonium Fluosilicate). Records of the Geological Survey of India, Calcutta: 59: 233.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Cryptohalite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/cryptohalite-1163},
  note      = {Accessed 2026-05-11}
}