Barlowite

Cu4BrF(OH)6
IMA status
  • Approved
IMA symbol
Blw
IMA approved
2010
Also known as
  • Barlowiet
  • IMA2010-020

Where it forms, where it's found

Geological setting

among secondary Cu minerals formed in cavities in cuprite-rich rocks, by oxidation of primary Cu mineralization under low-temperature conditions

Type locality
Great Australia Mine
  1. Cloncurry
  2. Cloncurry Shire
  3. Queensland
  4. Australia

-20.7195°, 140.5107°

2recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102 – 2.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Blue
Streak
Sky blue
Tenacity
brittle
Cleavage
Perfect

on (001)

Fracture
Irregular/Uneven
Density
4.21 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.833 – 1.845
Surface relief
Very high
Principal indices
nω 1.840 – 1.845 · nε 1.833 – 1.840
Pleochroism
Non-pleochroic
Michel-Lévy diagramhighlighted lineδ = 0.0060
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]60 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation60 nm
Order1st order
XPL colour

Crystallography

Crystal system
Hexagonal
Space group
P63/mmc
Cell parameters
a = 6.6786(2) Å · c = 9.2744(3) Å
Unit cell volume
358.25 ų
Z
2
Morphology

Thin platy, hexagonal crystals up to 0.5 mm wide.

Type-locality form

Thin blue, platy, hexagonal crystals up to 0.5 mm wide in a cuprite-quartz-goethite matrix.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
29CuCopperCopper463.546254.184
55.85%
8OOxygenOxygen615.99995.994
21.09%
35BrBromineBromine179.90479.904
17.56%
9FFluorineFluorine118.99818.998
4.17%
1HHydrogenHydrogen61.0086.048
1.33%
Total455.128100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Cl

Synonyms

  • Barlowiet
  • IMA2010-020

In other languages

German
Barlowit · IMA 2010-020
Italian
barlowite

Classification

Strunz
10th ed.

3.DA.15

  • 3HalidesClass
  • 3.DOxyhalides, hydroxyhalides and related double halidesDivision
  • 3.DAWith Cu, etc., without PbGroup
  • 3.DA.15BarlowiteSpecies
Dana
8th ed.

10.05.06.02

  • 10Oxyhalides and HydroxyhalidesClass
  • 10.05Am(O,OH)pXqType
  • 10.05.06— unnamed intermediate level —Group
  • 10.05.06.02BarlowiteSpecies

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 2010Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2010) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) CNMNC Newsletter No 4. Mineralogical Magazine, 74 (4) 797-800 doi:10.1180/s0026461x00038925 DOI: 10.1180/s0026461x00038925
  2. 2014Han, Tian-Heng, Singleton, John, Schlueter, John A. (2014) Barlowite: A Spin-1/2Antiferromagnet with a Geometrically Perfect Kagome Motif. Physical Review Letters, 113 (22). doi:10.1103/physrevlett.113.227203DOI: 10.1103/physrevlett.113.227203
  3. 2014Elliott, Peter, Cooper, Mark A., Pring, Allan (2014) Barlowite, Cu4FBr(OH)6, a new mineral isotructural with claringbullite: description and crystal structure. Mineralogical Magazine, 78 (7) 1755-1762 doi:10.1180/minmag.2014.078.7.17DOI: 10.1180/minmag.2014.078.7.17
  4. 2015Gati, Elena, Wolf, Bernd, Schlueter, John A., Lang, Michael (2015) Dilatometric Studies on Single Crystalline Barlowite – A Structurally Perfect Spin-1/2 Kagome System. Physics Procedia, 75. 597-604 doi:10.1016/j.phpro.2015.12.076DOI: 10.1016/j.phpro.2015.12.076
  5. 2016(2016) Barlowite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Barlowite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/barlowite-40276},
  note      = {Accessed 2026-05-11}
}