Bementite

Mn7Si6O15(OH)8
IMA status
  • Approved
  • Grandfathered
IMA symbol
Bem
Discovered
1887
Also known as
  • Bementiet
  • Bementite (of Koenig)

Where it forms, where it's found

Geological setting

Zinc-iron oxide ore deposit hosted in marble.

Found in low-grade metamorphic manganese silicate deposits

Type locality
Trotter Mine
  1. Franklin Mine
  2. Franklin
  3. Sussex County
  4. New Jersey
  5. USA

41.1178°, -74.5875°

171recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789106/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Brown · dark brown · golden brown · grayish-yellow

Lighter when fresh, weathering darker. Fresh material is transparent in splinters, weathering opaque.

Streak
White
Tenacity
flexible
Cleavage
Perfect

(001) perfect, (100) and (010) very good.

Fracture
Splintery
Density
2.9 g/cm³

Optical

Optical type
Biaxial
Refractive index
1.602 – 1.65
Surface relief
Moderate
Principal indices
nα 1.602 – 1.624 · nβ 1.632 – 1.65 · nγ 1.632 – 1.65
Birefringence
0.028
Pleochroism
Weak

Colorless, pale yellow

Dispersion
weak
Extinction
X ⊥ {001}.
UV response
Not fluorescent in UV.
Michel-Lévy diagramhighlighted lineδ = 0.0280
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]280 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation280 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 7.5 Å · b = 9.8 Å · c = 5.65 Å
Cell angles
β = 90 °
Ratio a:b:c
1 : 1.307 : 0.753
Z
1
Morphology

Micaceous aggregates or plates are typical. Felted aggregates of fibers or plates.

Type-locality form

Pale grayish yellow stellate masses, resembling karpholite or pyrophyllite.

Comment

Better calculations obtained from Orthorhombic cell.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
25MnManganeseManganese754.938384.566
41.39%
8OOxygenOxygen2315.999367.977
39.60%
14SiSiliconSilicon628.085168.510
18.14%
1HHydrogenHydrogen81.0088.064
0.87%
Total929.117100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Al
  • Fe
  • Zn
  • Mg
  • Ca

Synonyms

  • Bementiet
  • Bementite (of Koenig)

In other languages

French
bémentite
German
Bementit
Spanish
Bementita
Italian
bementite
Chinese
蜡硅锰矿

Classification

Strunz
10th ed.

9.EE.05

  • 9SilicatesClass
  • 9.EPhyllosilicatesDivision
  • 9.EESingle tetrahedral nets of 6-membered rings connected by octahedral nets or octahedral bandsGroup
  • 9.EE.05BementiteSpecies
Dana
8th ed.

78.05.02.01

  • 78Unclassified SilicatesClass
  • 78.05Unclassified silicates possible phyllosilicatesType
  • 78.05.02— unnamed intermediate level —Group
  • 78.05.02.01BementiteSpecies
CIM

14.17.8

  • 14Silicates not Containing AluminumClass
  • 14.17Silicates of MnGroup
  • 14.17.8BementiteSpecies

Group, growth & confusion

Often grow together
2 minerals

Literature, links & citation

Citations
  1. 1888Koenig, G.A. (1888) Preliminary note on a new mineral species from Franklin, N.J.. Proceedings of the Academy of Natural Sciences of Philadelphia, 1887, 310-311.
  2. 1921Pardee, J. T.; Larsen, E. S., Jr.; Steiger, George (1921): Bementite and neotocite from western Washington, with conclusions as to the identity of bementite and caryopilite. Journal of the Washington Academy of Sciences, 11, 25-32.
  3. 1925Larsen, Esper S. (1925) The identity of ectropite and bementite. American Mineralogist, 10 (11) 418-421
  4. 1929Smitheringale, W.V. (1929) Notes on etching tests and X-ray examination of some manganese minerals. Economic Geology, 24(5), 481-505.
  5. 1955Shirozu, Haruo, Hirowatari, Fumitoshi (1955) Bementite from the Tokuzawa mine, Fukushima Prefecture. The Journal of the Japanese Association of Mineralogists, Petrologists and Economic Geologists, 39 (6) 241-248 doi:10.2465/ganko1941.39.241 DOI: 10.2465/ganko1941.39.241
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Bementite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/bementite-621},
  note      = {Accessed 2026-05-11}
}