Where it forms, where it's found
- Geological setting
Concretion in an unconsolidated glacial sedimentary deposit.
A major manganese-bearing mineral of many soils; a common alteration product of manganese-rich mineral deposits; a component of bacterially-precipitated manganese oxides; an important constituent of "desert varnish" and marine manganese nodules.
- Type locality
- Birness
- Ellon
- Aberdeenshire
- Scotland
- UK
57.4032°, -1.9929°
Physical
Optical
- Optical type
- Uniaxial (-)
- Refractive index
- 1.69 – 1.73
- Surface relief
- High
- Principal indices
- nω 1.73 · nε 1.69
- Birefringence
- 0.040
- Dispersion
- weak to moderate
- Extinction
- Parallel. Refractive indices not far from pyrochroite.
- UV response
- Not fluorescent in UV
- Notes
The mineral is pseudo-uniaxial (-); an identification by optical properties is impossible.
Crystallography
- Space group
- C2/m
- Cell parameters
- a = 5.175 Å · b = 2.850 Å · c = 7.337 Å
- Cell angles
- β = 103.18 °
- Ratio a:b:c
- 1 : 0.551 : 1.418
- Z
- 1
- Morphology
Rarely in platelets, to 50 µm; commonly extremely finely crystalline, spherulitic, cellular. Rarely as divergent sprays of acicular crystals.
- Type-locality form
Black coating or cement on pebbles.
- Comment
Z also given as 0.5
Chemical composition
- Impurities
- Cl
- Co
- Cu
- Fe
- K
- Ni
- Mg
- S
- Si
Synonyms
- Birnessiet
- Delta-MnO2
- Manganous Manganite
- δ-MnO2
In other languages
- French
- Birnessite
- German
- Birnessit
- Spanish
- Birnessita
- Italian
- birnessite
- Japanese
- バーネス鉱
- Chinese
- 水钠锰矿
- Russian
- Бернессит
Classification
4.FL.45
- 4OxidesClass
- 4.FHydroxides (without V or U)Division
- 4.FLHydroxides with H2O +- (OH); sheets of edge-sharing octahedraGroup
- 4.FL.45BirnessiteSpecies
07.05.03.01
- 07Multiple OxidesClass
- 07.05(AB)2X3Type
- 07.05.03— unnamed intermediate level —Group
- 07.05.03.01BirnessiteSpecies
7.18.11
- 7Oxides and HydroxidesClass
- 7.18Oxides of MnGroup
- 7.18.11BirnessiteSpecies
Group, growth & confusion
Literature, links & citation
- 1944McMurdie, H.F. (1944) Microscopic and diffraction studies on dry cells and their raw materials. Transactions of the Electrochemical Society: 86: 313. [M.A. 9-227.]
- 1945Feitknecht, W., Marti, W. (1945) Über die Oxydation von Mangan(II)-hydroxyd mit molekularem Sauerstoff. Helvetica Chimica Acta, 28 (1). 129-148 doi:10.1002/hlca.19450280113DOI: 10.1002/hlca.19450280113
- 1948McMurdie, H.F., Golovato, E. (1948) Study of the modifications of manganese dioxide. Journal of research of the National Bureau of Standards: 41: 589-600.
- 1956Jones, L. H. P., Milne, Angela A. (1956) Birnessite, a new manganese oxide mineral from Aberdeenshire, Scotland. Mineralogical Magazine and Journal of the Mineralogical Society, 31 (235) 283-288 doi:10.1180/minmag.1956.031.235.01 DOI: 10.1180/minmag.1956.031.235.01
- 1957Fleischer, M. (1957) New mineral names. American Mineralogist, 42 (5-6). 440-444
@misc{mineral2026,
author = {Mineral Index editorial board},
title = {Birnessite — Mineral Index},
year = {2026},
url = {https://mineralindex.org/minerals/birnessite-680},
note = {Accessed 2026-05-11}
}

