Birnessite

(Na,Ca,K)0.6(Mn4+,Mn3+)2O4 · 1.5H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Bir
Discovered
1956
Also known as
  • Birnessiet
  • Delta-MnO2
  • Manganous Manganite
  • +1 more

Where it forms, where it's found

Geological setting

Concretion in an unconsolidated glacial sedimentary deposit.

A major manganese-bearing mineral of many soils; a common alteration product of manganese-rich mineral deposits; a component of bacterially-precipitated manganese oxides; an important constituent of "desert varnish" and marine manganese nodules.

Type locality
Birness
  1. Ellon
  2. Aberdeenshire
  3. Scotland
  4. UK

57.4032°, -1.9929°

195recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789101.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Opaque
Colour
Black · dark brown in transmitted light
Streak
Dark brown to brown
Tenacity
brittle
Cleavage

Structure suggests a cleavage might be observable on

Density
3 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.69 – 1.73
Surface relief
High
Principal indices
nω 1.73 · nε 1.69
Birefringence
0.040
Dispersion
weak to moderate
Extinction
Parallel. Refractive indices not far from pyrochroite.
UV response
Not fluorescent in UV
Notes

The mineral is pseudo-uniaxial (-); an identification by optical properties is impossible.

Michel-Lévy diagramhighlighted lineδ = 0.0400
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]400 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation400 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/m
Cell parameters
a = 5.175 Å · b = 2.850 Å · c = 7.337 Å
Cell angles
β = 103.18 °
Ratio a:b:c
1 : 0.551 : 1.418
Z
1
Morphology

Rarely in platelets, to 50 µm; commonly extremely finely crystalline, spherulitic, cellular. Rarely as divergent sprays of acicular crystals.

Type-locality form

Black coating or cement on pebbles.

Comment

Z also given as 0.5

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
25MnManganeseManganese454.938219.752
59.06%
8OOxygenOxygen5.515.99987.995
23.65%
20CaCalciumCalcium0.640.07824.047
6.46%
19KPotassiumPotassium0.639.09823.459
6.31%
11NaSodiumSodium0.622.99013.794
3.71%
1HHydrogenHydrogen31.0083.024
0.81%
Total372.070100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Cl
  • Co
  • Cu
  • Fe
  • K
  • Ni
  • Mg
  • S
  • Si

Synonyms

  • Birnessiet
  • Delta-MnO2
  • Manganous Manganite
  • δ-MnO2

In other languages

French
Birnessite
German
Birnessit
Spanish
Birnessita
Italian
birnessite
Japanese
バーネス鉱
Chinese
水钠锰矿
Russian
Бернессит

Classification

Strunz
10th ed.

4.FL.45

  • 4OxidesClass
  • 4.FHydroxides (without V or U)Division
  • 4.FLHydroxides with H2O +- (OH); sheets of edge-sharing octahedraGroup
  • 4.FL.45BirnessiteSpecies
Dana
8th ed.

07.05.03.01

  • 07Multiple OxidesClass
  • 07.05(AB)2X3Type
  • 07.05.03— unnamed intermediate level —Group
  • 07.05.03.01BirnessiteSpecies
CIM

7.18.11

  • 7Oxides and HydroxidesClass
  • 7.18Oxides of MnGroup
  • 7.18.11BirnessiteSpecies

Group, growth & confusion

In the same group
2 members
Often grow together
1 mineral
Commonly confused with
2 minerals

Literature, links & citation

Citations
  1. 1944McMurdie, H.F. (1944) Microscopic and diffraction studies on dry cells and their raw materials. Transactions of the Electrochemical Society: 86: 313. [M.A. 9-227.]
  2. 1945Feitknecht, W., Marti, W. (1945) Über die Oxydation von Mangan(II)-hydroxyd mit molekularem Sauerstoff. Helvetica Chimica Acta, 28 (1). 129-148 doi:10.1002/hlca.19450280113DOI: 10.1002/hlca.19450280113
  3. 1948McMurdie, H.F., Golovato, E. (1948) Study of the modifications of manganese dioxide. Journal of research of the National Bureau of Standards: 41: 589-600.
  4. 1956Jones, L. H. P., Milne, Angela A. (1956) Birnessite, a new manganese oxide mineral from Aberdeenshire, Scotland. Mineralogical Magazine and Journal of the Mineralogical Society, 31 (235) 283-288 doi:10.1180/minmag.1956.031.235.01 DOI: 10.1180/minmag.1956.031.235.01
  5. 1957Fleischer, M. (1957) New mineral names. American Mineralogist, 42 (5-6). 440-444
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Birnessite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/birnessite-680},
  note      = {Accessed 2026-05-11}
}