Todorokite

(Na,Ca,K,Ba,Sr)1-x(Mn,Mg,Al)6O12 · 3-4H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Tdr
Discovered
1934
Also known as
  • Delatorreite
  • Todorokiet

Where it forms, where it's found

Geological setting

Common in ocean floor manganese nodules; found in manganese oxide deposits; late stage coating in granite pegmatite

Type locality
Todoroki mine
  1. Yoichi District
  2. Shiribeshi Subprefecture
  3. Hokkaidō Prefecture
  4. Japan

43.0083°, 140.9250°

448recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789101.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Opaque
Colour
Purplish gray · brown to black · brown in transmitted light
Streak
Brown, black, lead-gray
Tenacity
brittle
Cleavage
Perfect

(100) and (010) perfect.

Fracture
Splintery
Density
3.67 g/cm³

Optical

Optical type
Biaxial (-)
Refractive index
2.31 – 2.35
Surface relief
Very high
Principal indices
nα 2.31 · nβ 2.35
Pleochroism
Visible

Pleochroic in brown.

Extinction
Y=b, Z>X
UV response
Not fluorescent in ultraviolet

Crystallography

Crystal system
Monoclinic
Space group
#13
Cell parameters
a = 9.75 Å · b = 2.84 Å · c = 9.59 Å
Cell angles
β = 90 °
Ratio a:b:c
1 : 0.291 : 0.984
Z
1
Morphology

Spongy banded and/or reniform aggregates composed of minute lathlike to fibrous crystals. Crystals flattened (010) and elongated [001] with terminal edges inclined about 60° and 70° to [001].

Twinning

Contact twins with c ^ ć about 60°.

Type-locality form

Very fine fibrous flakes, < 0.05 mm in length. The flakes are arranged in lamellar layers, in which the lamellae are vertical to the surface of the layer.

Comment

β may be variable; formerly given as orthorhombic or tetragonal

Crystal structure

Chemical composition

Impurities
  • Ba
  • K
  • Na

Synonyms

  • Delatorreite
  • Todorokiet

In other languages

German
Todorokit
Spanish
Todorokita
Italian
todorokite
Japanese
轟石
Russian
Тодорокит

Classification

Strunz
10th ed.

4.DK.10

  • 4OxidesClass
  • 4.DMetal: Oxygen = 1:2 and similarDivision
  • 4.DKWith large (+- medium-sized) cations; tunnel structuresGroup
  • 4.DK.10TodorokiteSpecies
Dana
8th ed.

07.08.01.01

  • 07Multiple OxidesClass
  • 07.08AB3X7Type
  • 07.08.01— unnamed intermediate level —Group
  • 07.08.01.01TodorokiteSpecies
CIM

7.4.19

  • 7Oxides and HydroxidesClass
  • 7.4Oxides of Be, Mg and the alkaline earthsGroup
  • 7.4.19TodorokiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1934Yoshimura, T. (1934) Todorokite, a new manganese mineral from the Todoroki Mine, Hokkaido, Japan. Journal of the Faculty of Science, Hokkaido University. Series 4, Geology and mineralogy, 2 (4). 289-297
  2. 1935Foshag, W.F. (1935) New mineral names. American Mineralogist: 20: 678-678.
  3. 1960Levinson, A. A. (1960) Second occurrence of todorokite. American Mineralogist, 45 (7-8) 802-807
  4. 1960Frondel, C., Marvin, U. B., Ito, J. (1960) New occurrences of todorokite. American Mineralogist, 45 (11-12) 1167-1173
  5. 1967Radtke, Arthur S., Taylor, Charles M., Hewett, D. F. (1967) Aurorite, argentian todorokite, and hydrous silver-bearing lead manganese oxide. Economic Geology, 62 (2) 186-206 doi:10.2113/gsecongeo.62.2.186DOI: 10.2113/gsecongeo.62.2.186
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Todorokite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/todorokite-3988},
  note      = {Accessed 2026-05-11}
}