Bischofite

MgCl2 · 6H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Bsf
Discovered
1877
Also known as
  • Bischofiet
  • Bischofite (of Ochsenius)
  • Bischofitt

Where it forms, where it's found

Geological setting

In saline deposits; probably in part formed from carnallite

Type locality
Friedrichshall potash mine
  1. Staßfurt
  2. Salzlandkreis
  3. Saxony-Anhalt
  4. Germany

51.8406°, 11.6069°

44recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789101 – 2/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Colourless to white · colourless in transmitted light
Streak
White
Fracture
Irregular/Uneven · Conchoidal
Density
1.591 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 79° · 2V calc = 76°
Refractive index
1.495 – 1.528
Surface relief
Moderate
Principal indices
nα 1.495 · nβ 1.507 · nγ 1.528
Dispersion
r > v, weak
Extinction
X = b; Y ∧ c = 9.5°.
Michel-Lévy diagramhighlighted lineδ = 0.0330
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]330 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation330 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/m
Cell parameters
a = 9.8607 Å · b = 7.1071 Å · c = 6.0737 Å
Cell angles
β = 93.758 °
Ratio a:b:c
1 : 0.721 : 0.616
Z
2
Morphology

Crystals short prismatic along [001]; commonly foliated, fibrous, crystalline granular, also massive

Twinning

May twin polysynthetically under pressure

Comment

synthetic material

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen615.99995.994
47.22%
17ClChlorineChlorine235.45070.900
34.87%
12MgMagnesiumMagnesium124.30524.305
11.96%
1HHydrogenHydrogen121.00812.096
5.95%
Total203.295100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Ca
  • S

Synonyms

  • Bischofiet
  • Bischofite (of Ochsenius)
  • Bischofitt

In other languages

German
Bischofit
Spanish
Bischofita
Italian
Bischofite
Japanese
ビショフ石
Chinese
水氯镁石
Simplified Chinese
水氯镁石
Russian
Бишофит
Arabic
بيشوفيت

Classification

Strunz
10th ed.

3.BB.15

  • 3HalidesClass
  • 3.BSimple halides, with H2ODivision
  • 3.BBM:X = 1:2Group
  • 3.BB.15BischofiteSpecies
Dana
8th ed.

09.02.09.01

  • 09Normal HalidesClass
  • 09.02AX2Type
  • 09.02.09Bischofite GroupGroup
  • 09.02.09.01BischofiteSpecies
CIM

8.4.3

  • 8Halides - Fluorides, Chlorides, Bromides and Iodides; also Fluoborates and FluosilicatesClass
  • 8.4Halides of the alkaline earths and MgGroup
  • 8.4.3BischofiteSpecies

Group, growth & confusion

Often grow together
2 minerals

Literature, links & citation

Citations
  1. 1877Ochsenius, C. (1877) Die Bildung der Steinsalzlager und ihrer Mutterlaugensalze [The formation of rock salt deposits and their mother liquor salts] - unter specieller Berücksichtigung der Flöze von Douglashall in der Egeln´schen Mulde [with special consideration of the Douglashall seams in the Egeln'sche Mulde]. Pfeffer, Halle.
  2. 1877Ochsenius, C. (1877): Jahresbericht über die Fortschritte der Chemie und verwandter Theile anderer Wissenschaften: 1284, 1285.
  3. 1877Ochsenius, C. (1877): Zeitschrift für Kristallographie, Mineralogie und Petrographie, Leipzig: 1: 414.
  4. 1904Przibylla (1904) Centralblatt für Mineralogie, Geologie und Paleontologie, Stuttgart: 238.
  5. 1905Dewar (1905) Chem. News: 91: 216.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Bischofite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/bischofite-681},
  note      = {Accessed 2026-05-11}
}