Bottinoite

NiSb5+2(OH)12 · 6H2O
IMA status
  • Approved
IMA symbol
Bot
IMA approved
1991
Also known as
  • Bottinoiet
  • Dörnbergit
  • Dörnbergite
  • +1 more

Where it forms, where it's found

Geological setting

In an oxidized hydrothermal base-metal deposit

Adjacent to and incrusting ullmannite in oxidized hydrothermal base-metal deposits

Type locality
Bottino Mine
  1. Stazzema
  2. Lucca Province
  3. Tuscany
  4. Italy

43.9914°, 10.2583°

18recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Pale blue to pale blue-green
Streak
Very light blue
Tenacity
brittle
Fracture
Conchoidal
Density
2.83 g/cm³

Optical

Optical type
Uniaxial (+)
Refractive index
1.6 – 1.605
Surface relief
Moderate
Principal indices
nω 1.6 · nε 1.605
Michel-Lévy diagramhighlighted lineδ = 0.0050
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]50 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation50 nm
Order1st order
XPL colour

Crystallography

Crystal system
Trigonal
Space group
#75
Cell parameters
a = 16.026 Å · c = 9.795 Å
Z
6
Morphology

Crystals tabular on (0001), with (1010), in rose-like and spherulitic aggregates, to 3 mm.

Twinning

Inability to solve the structure was attributed to possible twinning. Structure was subsequently solved in P3, with twinning taken into account.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1815.999287.982
46.87%
51SbAntimonyAntimony2121.760243.520
39.64%
28NiNickelNickel158.69358.693
9.55%
1HHydrogenHydrogen241.00824.192
3.94%
Total614.387100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Bottinoiet
  • Dörnbergit
  • Dörnbergite
  • IMA1991-029

In other languages

German
Bottinoit · IMA 1991-029
Spanish
Bottinoíta
Italian
Bottinoite

Classification

Strunz
10th ed.

4.FH.05

  • 4OxidesClass
  • 4.FHydroxides (without V or U)Division
  • 4.FHHydroxides with H2O +- (OH); insular octahedraGroup
  • 4.FH.05BottinoiteSpecies
Dana
8th ed.

06.03.09.01

  • 06Hydroxides and Oxides Containing HydroxylClass
  • 06.03X(OH)3Type
  • 06.03.09— unnamed intermediate level —Group
  • 06.03.09.01BottinoiteSpecies

Group, growth & confusion

In the same group
1 members

Literature, links & citation

Citations
  1. 1992Bonazzi, Paola, Menchetti, Silvio, Caneschi, Andrea, Magnanelli, Stefano (1992) Bottinoite, Ni(H2O)6[Sb(OH)6]2, a new mineral from the Bottino mine, Alpi Apuane, Italy. American Mineralogist, 77 (11-12) 1301-1304
  2. 1993Clark, A.M. (1993) Bottinoite, a mineral new to Britain. Mineralogical Magazine: 57: 543-544.
  3. 1996Bonazzi, Paola, Mazzi, Fiorenzo (1996) Bottinoite, Ni(H2O)6[Sb(OH)6]2; crystal structure, twinning, and hydrogen-bond model. American Mineralogist, 81 (11) 1494-1500 doi:10.2138/am-1996-11-1220 DOI: 10.2138/am-1996-11-1220
  4. 1997Anthony, John Williams, Bideaux, Richard A., Bladh, Kenneth W., Nichols, Monte C. - Ed. (1997) Handbook of Mineralogy Vol. 3 - Halides, Hydroxides, Oxides. Mineral Data Publishing, Tucson, Arizona. p.1-682.
  5. 2005(2005) Bottinoite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Bottinoite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/bottinoite-735},
  note      = {Accessed 2026-05-11}
}