Brandholzite

MgSb2(OH)12 · 6H2O
IMA status
  • Approved
IMA symbol
Bdh
IMA approved
1998
Also known as
  • Brandholziet
  • IMA1998-017

Where it forms, where it's found

Geological setting

An alteration product of stibnite within a zone of oxidation.

Oxidation zone of Sb ore deposits.

Type locality
Schmidten shaft
  1. Fürstenzeche mine
  2. Brandholz
  3. Goldkronach
  4. Bayreuth District
  5. Upper Franconia
  6. Bavaria
  7. Germany
7recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102 – 3/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Transparency
Transparent
Colour
Colourless
Streak
White
Tenacity
brittle
Cleavage
None Observed
Fracture
Conchoidal
Density
2.65 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.569 – 1.57
Surface relief
Moderate
Principal indices
nω 1.570 · nε 1.569
UV response
Not fluorescent.
Michel-Lévy diagramhighlighted lineδ = 0.0010
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]10 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation10 nm
Order1st order
XPL colour

Crystallography

Crystal system
Trigonal
Space group
#75
Cell parameters
a = 16.119 Å · c = 9.868 Å
Z
6
Morphology

Tabular hexagonal crystals with predominant forms (1010) and (0001).

Twinning

On (1010).

Type-locality form

Tabular, hexagonal crystals up to ~1 mm in diameter (but mostly <0.5 mm), often forming rose-like aggregates.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1815.999287.982
49.65%
51SbAntimonyAntimony2121.760243.520
41.99%
12MgMagnesiumMagnesium124.30524.305
4.19%
1HHydrogenHydrogen241.00824.192
4.17%
Total579.999100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Brandholziet
  • IMA1998-017

In other languages

German
Brandholzit · IMA 1998-017
Italian
Brandholzite

Classification

Strunz
10th ed.

4.FH.05

  • 4OxidesClass
  • 4.FHydroxides (without V or U)Division
  • 4.FHHydroxides with H2O +- (OH); insular octahedraGroup
  • 4.FH.05BrandholziteSpecies

Group, growth & confusion

In the same group
1 members
Often grow together
1 mineral

Literature, links & citation

Citations
  1. www.goldbergknappen.de (n.d.) http://www.goldbergknappen.de/html/brandholzit.html
  2. 1852Heffter, L. (1852) Poggendorff’s Annalen der Physik und Chemie, 86, 418. (synthetic)
  3. 1998Friedrich, A., Wildner, M., Tillmanns, E. (1998) Strukturuntersuchung und Kristallchemie des neuen Minerals Mg(H2O)6[Sb(OH)6]2 sowie einiger isotyper synthetischer Antimonate MeII(H2O,NH3)6[Sb(OH)6]2 (MeII = Mg, Co, Cu) Mitteilungen der Österreichischen Mineralogischen Gesellschaft, 143. 276-278
  4. 2000Friedrich, Alexandra; Wildner, Manfred; Tillmanns, Ekkehart; Merz, Peter L. (2000) Crystal chemistry of the new mineral brandholzite, Mg(H2O)6[Sb(OH)6]2, and of the synthetic analogues M2+(H2O)6[Sb(OH)6]2 (M2+ = Mg, Co). American Mineralogist, 85 (3-4). 593-599 doi:10.2138/am-2000-0422 DOI: 10.2138/am-2000-0422
  5. 2003Friedrich, A., Mazzi, F., Wildner, M., Tillmanns, E. (2003) Isotypism of Co(H2O)6[Sb(OH)6]2 with brandholzite and bottinoite. American Mineralogist, 88 (2-3) 462-463
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Brandholzite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/brandholzite-7046},
  note      = {Accessed 2026-05-11}
}