Calcioandyrobertsite

KCaCu5(AsO4)4[As(OH)2O2] · 2H2O
IMA status
  • Approved
IMA symbol
Carb
IMA approved
1997
Also known as
  • Calcioandyrobertsiet
  • IMA1997-023

Where it forms, where it's found

Type locality
Tsumeb Mine (Ongopolo Mine)
  1. Tsumeb
  2. Oshikoto Region
  3. Namibia

-19.2270°, 17.7276°

4recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Colour
Intensely blue · electric blue
Tenacity
brittle
Cleavage
Distinct/Good

(100)

Fracture
Conchoidal
Density
4.011 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 50° · 2V calc = 48°
Refractive index
1.713 – 1.749
Surface relief
High
Principal indices
nα 1.713 · nβ 1.743 · nγ 1.749
Pleochroism
Non-pleochroic
Dispersion
weak
Extinction
X ∧ a = 12° (in β obtuse); Y = b; Z = c.
UV response
Not fluorescent.
Michel-Lévy diagramhighlighted lineδ = 0.0360
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]360 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation360 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
#15
Cell parameters
a = 9.81 Å · b = 10.034 Å · c = 9.975 Å
Cell angles
β = 101.84 °
Ratio a:b:c
1 : 1.023 : 1.017
Unit cell volume
960.98 ų
Z
2
Morphology

Platy habit with forms (100) (dominant), (210), (001), (102) and (011). Also in veinlets.

Twinning

No twinning observed.

Type-locality form

Lamellar intergrowth with andyrobertsite as plates, to 10 mm, that radiate from the center of an aggregate 1.4 cm long and 1 cm at the base.

Comment

1M polytype (O polytype is orthorhombic, space group <i>Pnma</i>, <i>a</i> = 19.647 Å, <i>b</i> = 10.087 Å, <i>c</i> = 9.903 Å)

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
33AsArsenicArsenic574.922374.610
33.16%
8OOxygenOxygen2215.999351.978
31.16%
29CuCopperCopper563.546317.730
28.13%
20CaCalciumCalcium140.07840.078
3.55%
19KPotassiumPotassium139.09839.098
3.46%
1HHydrogenHydrogen61.0086.048
0.54%
Total1129.542100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Calcioandyrobertsiet
  • IMA1997-023

In other languages

German
Calcioandyrobertsit · IMA 1997-023
Italian
Calcioandyrobertsite
Chinese
水砷钾钙铜石

Classification

Strunz
10th ed.

8.DH.50

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DHWith large and medium-sized cations, (OH, etc.):RO4 < 1:1Group
  • 8.DH.50CalcioandyrobertsiteSpecies

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1999Cooper, Mark A., Hawthorne, Frank C., Pinch, William W., Grice, Joel D. (1999) Andyrobertsite and Calcioandyrobertsite: Two New Minerals from the Tsumeb Mine, Tsumeb, Namibia. The Mineralogical Record, 30 (3) 181-186
  2. 2000Cooper, M. A., Hawthorne, F. C. (2000) Highly undersaturated anions in the crystal structure of andyrobertsite - calcio-andyrobertsite, a doubly acid arsenate of the form K(Cd,Ca)[Cu2+5(AsO4)4](H2O)2. The Canadian Mineralogist, 38 (4) 817-830 doi:10.2113/gscanmin.38.4.817 DOI: 10.2113/gscanmin.38.4.817
  3. 2004Sarp, Halil, Černý, Radovan (2004) Calcio-andyrobertsite-2O, KCaCu5(AsO4)4[AsO2(OH)2]·2H2O: its description, crystal structure and relation with calcio-andyrobertsite-1M. European Journal of Mineralogy, 16 (1) 163-169 doi:10.1127/0935-1221/2004/0016-0163 DOI: 10.1127/0935-1221/2004/0016-0163
  4. 2021(2021) Calcioandyrobertsite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Calcioandyrobertsite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/calcioandyrobertsite-6840},
  note      = {Accessed 2026-05-11}
}