Calzirtite

Ca2Zr5Ti2O16
IMA status
  • Approved
IMA symbol
Caz
Discovered
1961
Also known as
  • Calzirtiet

Where it forms, where it's found

Geological setting

In metasomatic calcite forsterite-magnetite rocks of an alkalic ultrabasic massif.

Type locality
Gornoozerskii carbonatite complex (Gornoe Ozero)
  1. Sakha
  2. Russia

59.9333°, 136.8833°

32recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789106 – 7/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Dark brown · nearly black
Streak
Brown
Tenacity
brittle
Density
4.90 g/cm³

Optical

Optical type
Uniaxial (+)
Refractive index
2.19 – 2.36
Surface relief
Very high
Principal indices
nω 2.19 – 2.27 · nε 2.26 – 2.36
Pleochroism
Non-pleochroic
Optical colour
Light gray
Anisotropism
pronounced
Bireflectance
Distinct in immersion, not observed in air
Internal reflections
Strong, reddish brown
Tropism
Anisotropic
UV response
Does not fluoresce
Michel-Lévy diagramhighlighted lineδ = 0.0800
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]800 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation800 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Tetragonal
Space group
I41/acd
Cell parameters
a = 15.094 Å · c = 10.043 Å
Z
8
Morphology

Prismatic, bipyramidal.

Twinning

Trillings

Parting
Two partings at ∼80◦
Type-locality form

Tabular concretions 3x4x1 mm in size, composed of complex trillings. Single crystals are tetragonal, prismatic, bipyramidal.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
40ZrZirconiumZirconium591.224456.120
51.36%
8OOxygenOxygen1615.999255.984
28.83%
22TiTitaniumTitanium247.86795.734
10.78%
20CaCalciumCalcium240.07880.156
9.03%
Total887.994100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Calzirtiet

In other languages

German
Calzirtit
Italian
calzirtite

Classification

Strunz
10th ed.

4.DL.10

  • 4OxidesClass
  • 4.DMetal: Oxygen = 1:2 and similarDivision
  • 4.DLWith large (+- medium-sized) cations; fluorite-type structuresGroup
  • 4.DL.10CalzirtiteSpecies
Dana
8th ed.

08.07.04.01

  • 08Multiple Oxides Containing Niobium, Tantalum or TitaniumClass
  • 08.07MiscellaneousType
  • 08.07.04— unnamed intermediate level —Group
  • 08.07.04.01CalzirtiteSpecies
CIM

7.10.6

  • 7Oxides and HydroxidesClass
  • 7.10Oxides of Zr and ThGroup
  • 7.10.6CalzirtiteSpecies

Group, growth & confusion

In the same group
2 members
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1961Fleischer, M. (1961) New mineral names. American Mineralogist, 46 (11-12). 1513-1520
  2. 1961Zdorik, T.B., Sidorenko, G.A., Bykova, A.V. (1961) A new titanozirconate of calcium-calzirtite. Doklady Akademii Nauk SSSR: 137: 681-684.
  3. 1961Pyatenko, Yu.A., Pudovkina, Z.V. (1961) The crystal structure of calcirtite; a new derivative structure of CaF2-CeO2 type. Soviet Physics - Crystallography: 6: 155-157.
  4. 1967Bulakh, A. G., Anastasenko, G. F., Dakhiha, L. M. (1967) Calzirtite from carbonatites of northern Siberia. American Mineralogist, 52 (11-12) 1880-1884
  5. 1967IMA (1967) International Mineralogical Association: Commission on New Minerals and Mineral Names. Mineralogical Magazine and Journal of the Mineralogical Society, 36 (277) 131-136 doi:10.1180/minmag.1967.036.277.20 DOI: 10.1180/minmag.1967.036.277.20
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Calzirtite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/calzirtite-871},
  note      = {Accessed 2026-05-11}
}