Hiärneite

Ca2Zr4Mn3+SbTiO16
IMA status
  • Approved
IMA symbol
Hiä
Also known as
  • Hiärneiet
  • IMA1996-040

Where it forms, where it's found

Geological setting

Skarn

Type locality
Långban Mine
  1. Långban Ore District
  2. Filipstad
  3. Värmland County
  4. Sweden

59.8554°, 14.2648°

1recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789107/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Red

In thin section it is weakly dichroic in orange and yellow-orange.

Cleavage
None Observed
Fracture
None observed
Density
5.44 g/cm³

Optical

Optical type
Uniaxial (+)
Refractive index
2.12 – 2.16
Surface relief
Very high
Principal indices
nω 2.12 · nε 2.16
Birefringence
Weakly dichroic in orange and yellow-orange.
Optical colour
Colourless to gray
Anisotropism
Weak
Internal reflections
Yellow
Tropism
Anisotropic
UV response
None
Michel-Lévy diagramhighlighted lineδ = 0.0400
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]400 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation400 nm
Order1st order
XPL colour

Crystallography

Crystal system
Tetragonal
Space group
I41/acd
Cell parameters
a = 15.264(1) Å · c = 10.089(2) Å
Z
8
Type-locality form

Single grains and in aggregates up to 0.5 mm wide. Individual crystals are subhedral, with a short-prismatic habit, and do not exceed 200 microns their greatest dimension.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
40ZrZirconiumZirconium491.224364.896
39.42%
8OOxygenOxygen1615.999255.984
27.66%
51SbAntimonyAntimony1121.760121.760
13.15%
20CaCalciumCalcium240.07880.156
8.66%
25MnManganeseManganese154.93854.938
5.94%
22TiTitaniumTitanium147.86747.867
5.17%
Total925.601100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Hiärneiet
  • IMA1996-040

In other languages

German
Hiärneit · IMA 1996-040 · IMA 21-G
Italian
hiärneite

Classification

Strunz
10th ed.

4.DL.10

  • 4OxidesClass
  • 4.DMetal: Oxygen = 1:2 and similarDivision
  • 4.DLWith large (+- medium-sized) cations; fluorite-type structuresGroup
  • 4.DL.10HiärneiteSpecies

Group, growth & confusion

In the same group
2 members
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1997Holtstam, Dan (1997) Hiärneite, a new, Zr-Sb oxide mineral isostructural with calzirtite, from Långban, Sweden. European Journal of Mineralogy, 9 (4) 843-848 doi:10.1127/ejm/9/4/0843 DOI: 10.1127/ejm/9/4/0843
  2. 1998Mandarino, Joseph A. (1998) Abstracts of New Mineral Descriptions. The Mineralogical Record, 29 (5) 467-479
  3. 1998Jambor, John L., Roberts, Andrew C. (1998) New mineral names. American Mineralogist, 83 (3-4) 400-403
  4. 2022(2022) Hiärneite. Handbook of Mineralogy. Mineralogical Society of America
  5. 2022Holtstam, Dan, Bindi, Luca (2022) Crystal structure and composition of hiärneite, Ca2Zr4Mn3+SbTiO16, and constitution of the calzirtite group. Mineralogical Magazine, 86 (2) 314-318 doi:10.1180/mgm.2022.19DOI: 10.1180/mgm.2022.19
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Hiärneite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/hiarneite-6994},
  note      = {Accessed 2026-05-11}
}