Chalcoalumite

CuAl4(SO4)(OH)12 · 3H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Cca
Discovered
1925
Also known as
  • Chalcoalumiet
  • Chalcoalumit
  • Chalcoalumita

Where it forms, where it's found

Type locality
Holbrook Mine
  1. Copper Queen Mine
  2. Queen Hill
  3. Bisbee
  4. Cochise County
  5. Arizona
  6. USA

31.4342°, -109.9092°

94recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Dull · vitreous
Transparency
Transparent · Translucent
Colour
Turquoise-green · pale blue · bluish-grey · colourless in transmitted light.
Streak
White
Tenacity
sectile
Cleavage
Distinct/Good

Several perfect probable. (100)

Density
2.29 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 15°
Refractive index
1.52 – 1.53
Surface relief
Moderate
Principal indices
nα 1.52 · nβ 1.52 · nγ 1.53
Birefringence
0.01
Pleochroism
Weak

X = pale green; Y = colorless; Z = robin's egg blue.

Dispersion
relatively strong r<v
Extinction
Y = b; Z ∧ c = 22°.
UV response
Not fluorescent in UV.
Notes

2V small.

Michel-Lévy diagramhighlighted lineδ = 0.0100
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]100 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation100 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
#9
Cell parameters
a = 17.09 Å · b = 8.92 Å · c = 10.22 Å
Cell angles
β = 95.88 °
Ratio a:b:c
1 : 0.522 : 0.598
Z
4
Morphology

Occurs as rather porous, botryoidal crusts comprised of minute, matted fibers. Relatively large, lath-like crystals coat the outsides of the structures.

Twinning

Twinning of the laths sometimes apparent with the composition face parallel to the long edge and nearly normal to the flat face. These exhibit re-entrant angles, with symmetrical faces and extinction.

Type-locality form

Thin crusts.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1915.999303.981
57.83%
13AlAluminiumAluminium426.982107.928
20.53%
29CuCopperCopper163.54663.546
12.09%
16SSulfurSulfur132.06032.060
6.10%
1HHydrogenHydrogen181.00818.144
3.45%
Total525.659100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Chalcoalumiet
  • Chalcoalumit
  • Chalcoalumita

In other languages

German
Chalkoalumit
Spanish
Calcoalumita
Italian
Calcoallumite · Calcoalumite · Chalcoalumite

Classification

Strunz
10th ed.

7.DD.75

  • 7SulfatesClass
  • 7.DSulfates (selenates, etc.) with additional anions, with H2ODivision
  • 7.DDWith only medium-sized cations; sheets of edge-sharing octahedraGroup
  • 7.DD.75ChalcoalumiteSpecies
Dana
8th ed.

31.03.01.01

  • 31Hydrated Sulfates Containing Hydroxyl or HalogenClass
  • 31.03(AB)5(XO4)Zq·xH2OType
  • 31.03.01— unnamed intermediate level —Group
  • 31.03.01.01ChalcoalumiteSpecies
CIM

25.2.19

  • 25SulphatesClass
  • 25.2Sulphates of Cu and AgGroup
  • 25.2.19ChalcoalumiteSpecies

Group, growth & confusion

In the same group
3 members

Literature, links & citation

Citations
  1. 1925Larsen, Esper S., Vassar, Helen E. (1925) Chalcoalumite, a new mineral from Bisbee, Arizona. American Mineralogist, 10 (4) 79-83
  2. 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
  3. 1971Williams, Sidney A., Khin, BaSaw (1971) Chalcoalumite from Bisbee, Arizona. The Mineralogical Record, 2 (3) 126-127
  4. 2005(2005) Chalcoalumite. Handbook of Mineralogy. Mineralogical Society of America
  5. 2012Kolitsch, U. & Brandstätter, F. (2012): 1772) Chalkoalumit, ein Chalkoalumit-ähnliches Mineral, Magnesiochromit, Pyrolusit, Ranciéit und Todorokit vom Magnesitbergbau Breitenau am Hochlantsch, Steiermark. Pp. 169-171 in Niedermayr, G. et al. (2012): Neue Mineralfunde aus Österreich LX. Carinthia II, 202./122., 123-180.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Chalcoalumite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/chalcoalumite-961},
  note      = {Accessed 2026-05-11}
}