Chapmanite

Fe3+2Sb3+(Si2O5)O3(OH)
IMA status
  • Approved
  • Grandfathered
IMA symbol
Cpm
Discovered
1924
Also known as
  • Antimon-Hypochlorite
  • Hoeferite
  • Höferite

Where it forms, where it's found

Geological setting

Oxidation zone of a silver deposit.

Type locality
Keeley-Frontier Mine
  1. South Lorrain Township
  2. Cobalt-Gowganda region
  3. Timiskaming District
  4. Ontario
  5. Canada

47.1992°, -79.5056°

26recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Olive green to deep yellow
Streak
Greenish yellow to deep yellow
Cleavage

When compact

Fracture
Irregular/Uneven · Conchoidal
Density
3.69 g/cm³

Optical

Optical type
Biaxial (-) · 2V calc = 32°
Refractive index
1.85 – 1.96
Surface relief
Very high
Principal indices
nα 1.85 · nβ 1.95 · nγ 1.96
Dispersion
none
Michel-Lévy diagramhighlighted lineδ = 0.1100
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]1100 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation1100 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
Cm
Cell parameters
a = 5.19 Å · b = 8.99 Å · c = 7.70 Å
Cell angles
β = 100.4 °
Ratio a:b:c
1 : 1.732 : 1.484
Z
2
Morphology

Crystals lath shaped, powdery, compact, massive.

Type-locality form

Pulverulent; olive-green.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen915.999143.991
33.13%
51SbAntimonyAntimony1121.760121.760
28.02%
26FeIronIron255.845111.690
25.70%
14SiSiliconSilicon228.08556.170
12.92%
1HHydrogenHydrogen11.0081.008
0.23%
Total434.619100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Al

Synonyms

  • Antimon-Hypochlorite
  • Hoeferite
  • Höferite

In other languages

German
Chapmanit · Höferit
Spanish
Chapmanita
Italian
Chapmanite
Chinese
羟硅锑铁矿

Classification

Strunz
10th ed.

9.ED.25

  • 9SilicatesClass
  • 9.EPhyllosilicatesDivision
  • 9.EDPhyllosilicates with kaolinite layers composed of tetrahedral and octahedral netsGroup
  • 9.ED.25ChapmaniteSpecies
Dana
8th ed.

71.01.03.02

  • 71Phyllosilicates Sheets of Six-membered RingsClass
  • 71.01Sheets of 6-membered rings with 1:1 layersType
  • 71.01.03Bismutoferrite groupGroup
  • 71.01.03.02ChapmaniteSpecies
CIM

17.7.20

  • 17Silicates Containing other AnionsClass
  • 17.7Silicates with vanadate, arsenate or antimonateGroup
  • 17.7.20ChapmaniteSpecies

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. Verryn, S.M.C. and Meulenbeeld, P.M.P.B. (2000) A new locality for chapmanite (Sb(OH)Fe2(SiO4)2) at a lead-silver-zinc deposit near Argent Station, Mpumalanga, South Africa. Neues Jahrbuch für Mineralogie, Geologie und Palaeontologie 2000 (2), 85-90.
  2. 1924WALKER, T.L. (1924): Chapmanite, a new hydrous ferrous silica-antimonate from South Lorrain, Ontario. Contributions to Canadian Mineralogy, University of Toronto, Geology Series 17, 5-8.
  3. 1925Foshag, W.F. (1925) New minerals: new species. American Mineralogist, 10, 39-41.
  4. 1958Milton, Charles, Axelrod, Joseph M., Ingram, Blanche (1958) Bismutoferrite, chapmanite and "hypochlorite". American Mineralogist, 43 (7-8) 656-670
  5. 1958Fleischer, M. (1958) New mineral names. American Mineralogist, 43, 623-626.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Chapmanite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/chapmanite-970},
  note      = {Accessed 2026-05-11}
}