Chiolite

Na5Al3F14
IMA status
  • Approved
  • Grandfathered
IMA symbol
Cio
Discovered
1846
Also known as
  • Arksudit
  • Arksudita
  • Arksudite
  • +9 more

Where it forms, where it's found

Geological setting

Cryolite-bearing pegmatite.

Type locality
Pit No. 69 (G.I. Gasberg's Topaz-Cryolite Pit)
  1. Ilmen Mountains
  2. Chelyabinsk Oblast
  3. Russia
7recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Nearly colourless · snow-white
Cleavage
Perfect

On (001); on (011) distinct.

Density
2.998 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.342 – 1.349
Surface relief
Low
Principal indices
nω 1.349 · nε 1.342
Michel-Lévy diagramhighlighted lineδ = 0.0070
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]70 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation70 nm
Order1st order
XPL colour

Crystallography

Crystal system
Tetragonal
Space group
#182
Cell parameters
a = 7.01 Å · c = 10.4 Å
Morphology

Crystals dipyramidal (011). Distinct crystals small and rare. Massive, granular.

Twinning

On (011), distorted into prismatic shapes at times.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
9FFluorineFluorine1418.998265.972
57.59%
11NaSodiumSodium522.990114.950
24.89%
13AlAluminiumAluminium326.98280.946
17.52%
Total461.868100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Arksudit
  • Arksudita
  • Arksudite
  • Arksutit
  • Arksutita
  • Arksutite
  • Chioliet
  • Chiolit
  • Chiolita
  • Chodneffite
  • Chodnewite
  • Nipholith

In other languages

French
chiolite
German
Chiolith
Italian
chiolite
Russian
хиолит

Classification

Strunz
10th ed.

3.CE.05

  • 3HalidesClass
  • 3.CComplex halidesDivision
  • 3.CEPhyllo-aluminofluoridesGroup
  • 3.CE.05ChioliteSpecies
Dana
8th ed.

11.06.11.01

  • 11Halide ComplexesClass
  • 11.06Aluminofluorides - Isolated OctahedraType
  • 11.06.11— unnamed intermediate level —Group
  • 11.06.11.01ChioliteSpecies
CIM

8.6.6

  • 8Halides - Fluorides, Chlorides, Bromides and Iodides; also Fluoborates and FluosilicatesClass
  • 8.6Halides of AlGroup
  • 8.6.6ChioliteSpecies

Group, growth & confusion

Often grow together
1 mineral

Literature, links & citation

Citations
  1. 1845von Wörth and Chodnev (1845-46) Verh. min. Ges.: 208 (as Chiolith).
  2. 1846Hermann, R., Auerback (1846) Untersuchungen russischer mineralien. 26) Ueber chiolith, ein neues mineral. Journal für Praktische Chemie: 37: 175-193 (188). (as Chiolith)
  3. 1848Rammelsberg (1848) Annalen der Physik, Halle, Leipzig: 74: 314.
  4. 1850Dana, James D. (1850) A System of Mineralogy (3rd ed.) G. P. Putnam. p.711
  5. 1862Koksharov, Nikolai (1862) Materialien zur Mineralogie Russlands Vol. 4. Carl Kray.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Chiolite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/chiolite-1006},
  note      = {Accessed 2026-05-11}
}