Cryolite

Na2NaAlF6
IMA status
  • Approved
  • Grandfathered
IMA symbol
Crl
Discovered
1799
Also known as
  • Alumine fluatée alkaline
  • Chryolith
  • Cryoliet
  • +3 more

Where it forms, where it's found

Geological setting

As a pegmatitic body in a granite stock intruded into gneiss.

Late stage mineral in granitic pegmatites, vapor phase mineral in rhyolites.

Type locality
Ivigtut Mine
  1. Ivigtut stock
  2. Arsuk Fjord
  3. Sermersooq
  4. Greenland

61.2061°, -48.1756°

48recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103 – 3.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous · Greasy
Transparency
Transparent · Translucent
Colour
Colourless · white · brown · grey · black · colourless in transmitted light.
Streak
White
Tenacity
brittle
Cleavage
None Observed
Fracture
Irregular/Uneven
Density
2.96 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 43° · 2V calc = 76°
Refractive index
1.3385 – 1.34
Surface relief
Low
Principal indices
nα 1.3385 – 1.339 · nβ 1.3389 – 1.339 · nγ 1.3396 – 1.34
Dispersion
r < v
Extinction
X = b; Z ∧ c = −44°.
Michel-Lévy diagramhighlighted lineδ = 0.0010
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]10 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation10 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 7.7564(3) Å · b = 5.5959(2) Å · c = 5.4024(2) Å
Cell angles
β = 90.18 °
Ratio a:b:c
1 : 0.721 : 0.697
Z
2
Morphology

Crystals usually cuboidal with c, , or modified by r, v, k; also short prismatic [001]. (110) faces striated [1_11], [1_1_1], or [1_10]. Massive, coarsely granular.

Twinning

Very common. Often repeated or polysynthetic with simultaneous occurrence of several twin laws, and reflecting the pseudo-orthorhombic symmetry of the unit cell. 1. By a 90° or 270° rotation on [110], penetration, common. 2. By a 180° rotation on [110], rhombic section (11_0), repeated, less common. 3. By a 120° rotation on [021], composition surface irregular; common, especially in granular material, as fine lamellae and probably always secondary. 4. By a 180° rotation on [1_11], rhombic section near (110), repeated; rare (not in granular material). 5. On (001) or by a 180° rotation on [100], composition plane (001). 6. On (100) or by a 180° rotation on [001], composition plane (100). 7. On (112), composition plane (112). 8. On (1_12), composition plane (112). 9. On (110), composition plane (110). 10. By a 180° rotation on [111], rhombic section near (11_0). 11. On (211). (Palache et al (1951), Dana's System of Mineralogy, 7th. ed., vol. 2: 111).

Parting
On (001) and (110), producing cuboidal forms.
Epitaxy

Oriented growths (artificial material).

Type-locality form

Massive white transparent to translucent.

Comment

Spacegroup: P21/n (Mitchell et al. 2016); at 5K, the structure is the same as that at RT

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
9FFluorineFluorine618.998113.988
54.30%
11NaSodiumSodium322.99068.970
32.85%
13AlAluminiumAluminium126.98226.982
12.85%
Total209.940100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Fe
  • Ca

Synonyms

  • Alumine fluatée alkaline
  • Chryolith
  • Cryoliet
  • Cryolithe
  • Eisstein
  • Thonerde mit Flussäure

In other languages

French
alumine fluatée alkaline · cryolite · cryolithe
German
Eisstein · Kryolith
Spanish
criolita
Italian
criolite · Cryolite
Portuguese
criolita · criolite · criolito
Japanese
氷晶石
Chinese
冰晶石
Simplified Chinese
冰晶石
Traditional Chinese
冰晶石
Russian
криолит
Arabic
كريوليت

Classification

Strunz
10th ed.

3.CB.15

  • 3HalidesClass
  • 3.CComplex halidesDivision
  • 3.CBNeso-aluminofluoridesGroup
  • 3.CB.15CryoliteSpecies
Dana
8th ed.

11.06.01.01

  • 11Halide ComplexesClass
  • 11.06Aluminofluorides - Isolated OctahedraType
  • 11.06.01Cryolite GroupGroup
  • 11.06.01.01CryoliteSpecies
CIM

8.6.5

  • 8Halides - Fluorides, Chlorides, Bromides and Iodides; also Fluoborates and FluosilicatesClass
  • 8.6Halides of AlGroup
  • 8.6.5CryoliteSpecies

Group, growth & confusion

In the same group
2 members
Often grow together
5 minerals

Literature, links & citation

Citations
  1. 1799Abildgaard, Nicolay Abraham (1799) Norwegische Titanerze und andre neue Fossilien [Norwegian titanium ores and other new fossils]. Allgemeines Journal der Chemie, S. 1 Vol. 2 (10). 502
  2. 1799Abildgaard, P. C. (1799) Sur plusieurs pierres nouvelles envoyées de Norwége; sur la désoxidation de l'oxide sur le gaz extrait de l'eau bouille [On several new stones sent from Norway; on the deoxidation of oxide on the gas extracted from boiled water]. Annales de Chimie ou Recueil de mémoires concernant la chimie et les arts qui en dependent, 32. 193-196
  3. 1800Karsten, D.L.G. (1800) Mineralogische Tabellen, Berlin. First edition (1800): 28: 73 (as Kryolith).
  4. 1800Klaproth (1800) Journal Phys.: 51: 473.
  5. 1800d' Andrada [e Silva], [José Bonifácio] (1800) Kurze Angabe der Eigenschaften und Kennzeichen einiger neuen Fossilien aus Schweden und Norwegen : nebst einigen chemischen Bemerkungen über dieselben [A brief description of the properties and characteristics of some new fossils from Sweden and Norway : together with some chemical remarks on the same]. Allgemeines Journal der Chemie, S. 1 Vol. 4 (19). 28-39
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Cryolite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/cryolite-1161},
  note      = {Accessed 2026-05-11}
}