Chivruaiite

Ca4(Ti,Nb)5(Si6O17)2(OH,O)5 · 13-14H2O
IMA status
  • Approved
IMA symbol
Cvr
Discovered
1978
IMA approved
2004
Also known as
  • Chivruaiiet
  • IMA2004-052

Where it forms, where it's found

Geological setting

Microcline vein in eudialyte-bearing lujavrite; astrophyllite-aegirine-microcline hydrothermal veins in foyaite within nepheline syenite in alkaline massifs.

Type locality
Chivruai river valley
  1. Lovozersky District
  2. Murmansk Oblast
  3. Russia
2recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Pale pink to colourless
Streak
White
Cleavage
Distinct/Good

on (100) and (010)

Fracture
Step-Like
Density
2.4 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 35 – 45° · 2V calc = 31°
Refractive index
1.612 – 1.705
Surface relief
High
Principal indices
nα 1.705 · nβ 1.627 · nγ 1.612
Pleochroism
Weak

X = b Y = a Z = c Z: pale-pink, X and Y: colourless

Dispersion
r < v
Michel-Lévy diagramhighlighted lineδ = 0.0930
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]930 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation930 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
#52
Cell parameters
a = 7.17 Å · b = 22.98 Å · c = 6.94 Å
Ratio a:b:c
1 : 3.205 : 0.968
Unit cell volume
1144.4 ų
Z
1
Morphology

Dominant faces: (100), (010), (001), (101), and (011)

Type-locality form

elongate-prismatic crystals up to 3 mm long, as well as radiating aggregates

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen5715.999911.943
42.53%
41NbNiobiumNiobium592.906464.530
21.66%
14SiSiliconSilicon1228.085337.020
15.72%
22TiTitaniumTitanium547.867239.335
11.16%
20CaCalciumCalcium440.078160.312
7.47%
1HHydrogenHydrogen311.00831.248
1.46%
Total2144.388100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Chivruaiiet
  • IMA2004-052

In other languages

German
Chivruaiit · IMA 2004-052
Italian
chivruaiite

Classification

Strunz
10th ed.

9.DG.45

  • 9SilicatesClass
  • 9.DInosilicatesDivision
  • 9.DGInosilicates with 3-periodic single and multiple chainsGroup
  • 9.DG.45ChivruaiiteSpecies

Group, growth & confusion

In the same group
3 members

Literature, links & citation

Citations
  1. 2006Men'shikov, Y. P. (2006) Chivruaiite, Ca4(Ti,Nb)5[(Si6O17)2[(OH,O)5]·13-14H2O, a new mineral from hydrothermal veins of Khibiny and Lovozero alkaline massifs. American Mineralogist, 91 (5) 922-928 doi:10.2138/am.2006.2032 DOI: 10.2138/am.2006.2032
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Chivruaiite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/chivruaiite-27495},
  note      = {Accessed 2026-05-11}
}