Haineaultite

(Na,Ca)5Ca(Ti,Nb)5Si12O34(OH,F)8 · 5H2O
IMA status
  • Approved
IMA symbol
Hnt
Discovered
1986
IMA approved
1997
Also known as
  • Haineaultiet
  • IMA1997-015
  • Unnamed (MSH UK-61)
  • +1 more

Where it forms, where it's found

Geological setting

In cavities of marble clods, at a contact of sodalite-syenite and nepheline-syenite.

Type locality
Poudrette quarry (De-Mix quarry
  1. Demix quarry
  2. Uni-Mix quarry
  3. Carrière Mont Saint-Hilaire
  4. MSH)
  5. Mont Saint-Hilaire
  6. La Vallée-du-Richelieu RCM
  7. Montérégie
  8. Québec
  9. Canada

45.5628°, -73.1417°

1recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103 – 4/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Pale honey-yellow · colourless to white · pale orange
Streak
White
Tenacity
brittle
Cleavage
Distinct/Good

on (100), (010) and (001)

Density
2.28 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 38° · 2V calc = 41°
Refractive index
1.599 – 1.696
Surface relief
Moderate
Principal indices
nα 1.599 · nβ 1.610 · nγ 1.696
Pleochroism
Non-pleochroic
Dispersion
None
UV response
weak yellowish under MW UV (as shown on <br /> https://www.mindat.org/photo-1243512.html
Notes

X = b; Y = c; Z = a.

Michel-Lévy diagramhighlighted lineδ = 0.0970
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]970 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation970 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
#38
Cell parameters
a = 7.024 Å · b = 23.15 Å · c = 6.953 Å
Ratio a:b:c
1 : 3.296 : 0.990
Unit cell volume
1130.84 ų
Z
1
Morphology

Predominant pinacoidal faces (100), (010) and (001), minor prism faces (011).

Type-locality form

Prismatic crystals to 6 mm, isolated or in fan-shaped aggregates.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen4715.999751.953
32.43%
41NbNiobiumNiobium592.906464.530
20.04%
14SiSiliconSilicon1228.085337.020
14.54%
20CaCalciumCalcium640.078240.468
10.37%
22TiTitaniumTitanium547.867239.335
10.32%
9FFluorineFluorine818.998151.984
6.56%
11NaSodiumSodium522.990114.950
4.96%
1HHydrogenHydrogen181.00818.144
0.78%
Total2318.384100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Haineaultiet
  • IMA1997-015
  • Unnamed (MSH UK-61)
  • Unnamed (MSH UK-61A)

In other languages

German
Haineaultit · IMA 1997-015
Spanish
Haineaultita
Italian
Haineaultite

Classification

Strunz
10th ed.

9.DG.50

  • 9SilicatesClass
  • 9.DInosilicatesDivision
  • 9.DGInosilicates with 3-periodic single and multiple chainsGroup
  • 9.DG.50HaineaultiteSpecies

Group, growth & confusion

In the same group
3 members

Literature, links & citation

Citations
  1. 2004McDonald, Andrew M., Chao, George Y. (2004) Haineauite, a new hydrated sodium calcium titanosilicate from Mont Saint-Hilaire, Quebec: description, structure determination and genetic implications. The Canadian Mineralogist, 42 (3) 769-780 doi:10.2113/gscanmin.42.3.769 DOI: 10.2113/gscanmin.42.3.769
  2. 2006Men'shikov, Y. P. (2006) Chivruaiite, Ca4(Ti,Nb)5[(Si6O17)2[(OH,O)5]·13-14H2O, a new mineral from hydrothermal veins of Khibiny and Lovozero alkaline massifs. American Mineralogist, 91 (5) 922-928 doi:10.2138/am.2006.2032 DOI: 10.2138/am.2006.2032
  3. 2013(2013) Haineaultite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Haineaultite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/haineaultite-25707},
  note      = {Accessed 2026-05-11}
}