Claudetite

As2O3
IMA status
  • Approved
  • Grandfathered
IMA symbol
Cdt
Discovered
1868
Also known as
  • Acide arsénieux prismatique
  • Arsenphyllite
  • Claudelite
  • +5 more

Where it forms, where it's found

Geological setting

In seams, in arsenopyrite ore.

Type locality
São Domingos Mine
  1. Corte do Pinto
  2. Mértola
  3. Beja
  4. Portugal

37.6696°, -7.4979°

39recorded occurrences
Source · OpenStreetMap

Varieties

Safety & handling

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Colourless · white
Streak
White
Tenacity
elastic
Cleavage
Perfect

on (010)

Fracture
Splintery
Density
4.14 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 58° · 2V calc = 78°
Refractive index
1.87 – 2.01
Surface relief
Very high
Principal indices
nα 1.87 · nβ 1.92 · nγ 2.01
Dispersion
strong
Michel-Lévy diagramhighlighted lineδ = 0.1400
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]1400 nm3rd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation1400 nm
Order3rd order
XPL colour

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 5.33 Å · b = 12.98 Å · c = 4.54 Å
Cell angles
β = 94.27 °
Ratio a:b:c
1 : 2.435 : 0.852
Z
4
Morphology

Thin plates on (010) and elongated [001] with (111) and (111) prominent, resembling selenite.

Twinning

On (100) as penetration or contact twins, common.

Type-locality form

Thin plates, resembling selenite.

Comment

Space Group: P21/n (synthetic)

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
33AsArsenicArsenic274.922149.844
75.74%
8OOxygenOxygen315.99947.997
24.26%
Total197.841100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Acide arsénieux prismatique
  • Arsenphyllite
  • Claudelite
  • Claudetiet
  • Prismatic Arsenious Acid
  • Rhombarsenit
  • Rhombarsenita
  • Rhombarsenite

In other languages

French
Claudétite
German
Claudetit
Spanish
claudetita · Rhombarsenita
Italian
claudetite
Chinese
白砷石
Russian
Клаудетит

Classification

Strunz
10th ed.

4.CB.45

  • 4OxidesClass
  • 4.CMetal: Oxygen = 2: 3,3: 5, and similarDivision
  • 4.CBWith medium-sized cationsGroup
  • 4.CB.45ClaudetiteSpecies
Dana
8th ed.

04.03.10.01

  • 04Simple OxidesClass
  • 04.03A2X3Type
  • 04.03.10Claudetite groupGroup
  • 04.03.10.01ClaudetiteSpecies
CIM

7.13.2

  • 7Oxides and HydroxidesClass
  • 7.13Oxides of As, Sb and BiGroup
  • 7.13.2ClaudetiteSpecies

Group, growth & confusion

In the same group
1 members
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1868Dana, James D., Brush, George Jarvis (1868) A System of Mineralogy (5th ed.). p.882
  2. 1934Palache, Charles (1934) Contributions to crystallography: claudetite; minasragrite; samsonite; native selenium; indium. American Mineralogist, 19 (5) 194-205
  3. 1934American Mineralogist: 19: 128 (1934).
  4. 1944Palache, Charles, Berman, Harry, Frondel, Clifford (1944) The System of Mineralogy (7th ed.) Vol. 1 - Elements, Sulfides, Sulfosalts, Oxides. John Wiley and Sons, New York.
  5. 1951Becker, K. A.; Plieth, K.; Stranski, I. N. (1951) Strukturuntersuchung der monoklinen Arsenikmodifikation Claudetit. Zeitschrift für anorganische und allgemeine Chemie, 266 (6). 293-301 doi:10.1002/zaac.19512660604DOI: 10.1002/zaac.19512660604
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Claudetite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/claudetite-1060},
  note      = {Accessed 2026-05-11}
}