Arsenolite

As2O3
IMA status
  • Approved
  • Grandfathered
IMA symbol
Aso
Discovered
1854
Also known as
  • Acide arsenieux
  • Acide arsenioso
  • Acido arsenioso
  • +18 more

Where it forms, where it's found

Type locality
St Andreasberg
  1. Braunlage
  2. Goslar District
  3. Lower Saxony
  4. Germany
265recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789101.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous · Silky
Transparency
Transparent
Colour
White · bluish · reddish to yellowish if impure with realgar or orpiment · colourless in transmitted light
Streak
White to pale yellowish white
Cleavage
Distinct/Good

on (111)

Fracture
Conchoidal
Density
3.86 g/cm³

Optical

Optical type
Isotropic
Surface relief
High
Principal indices
n 1.755
Tropism
Isotropic
Luminescence
None
Notes

May be anomalously anisotropic

Isotropy testPPL ↔ XPL diagnostic
PPL intrinsic colour; no change on stage rotation
XPL extinct at every orientation
Single index
n = 1.755

Crystallography

Crystal system
Isometric
Space group
#222
Cell parameters
a = 11.074 Å
Z
16
Morphology

Commonly as tiny octahedra, sometimes modified by the dodecahedron; also in aggregates or crusts, botryoidal, stalactitic, earthy to powdery.

Type-locality form

oxidation product of arsenic-bearing sulphides in hydrothermal veins

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
33AsArsenicArsenic274.922149.844
75.74%
8OOxygenOxygen315.99947.997
24.26%
Total197.841100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Acide arsenieux
  • Acide arsenioso
  • Acido arsenioso
  • Arsenic Blanc
  • Arsenic blanc natif
  • Arsenic oxide
  • Arsenico bianco
  • Arsenico blanco
  • Arsenicum cubicum
  • Arsenige Säure
  • Arsenikblomma
  • Arsenikkalk
  • Arsenious acid
  • Arsenious oxide
  • Arsenit
  • Arsenita
  • Arsenite
  • Arsenium calciforme
  • Arsenolitt
  • Natürlicher Arsenikkalk
  • White Arsenic

In other languages

French
Arsénolite
German
Arsenblüte · Arsenolith
Spanish
Arsenita · Arsenolita
Italian
Arsenolite
Chinese
砷华
Russian
Арсенолит
Arabic
أرسينوليت

Classification

Strunz
10th ed.

4.CB.50

  • 4OxidesClass
  • 4.CMetal: Oxygen = 2: 3,3: 5, and similarDivision
  • 4.CBWith medium-sized cationsGroup
  • 4.CB.50ArsenoliteSpecies
Dana
8th ed.

04.03.09.01

  • 04Simple OxidesClass
  • 04.03A2X3Type
  • 04.03.09— unnamed intermediate level —Group
  • 04.03.09.01ArsenoliteSpecies
CIM

7.13.1

  • 7Oxides and HydroxidesClass
  • 7.13Oxides of As, Sb and BiGroup
  • 7.13.1ArsenoliteSpecies

Group, growth & confusion

Often grow together
2 minerals
Commonly confused with
2 minerals

Literature, links & citation

Citations
  1. Chemical Abstracts: 88: 573 [abstract].
  2. 1747Wallerius, Johan Gotschalk (1747) Mineralogia, Eller Mineralriket, Indelt och beskrifvit. Uplagd pa Lars Sal. VII egen Kostnad, 479 pgs (224). (as Arsenicum nativum farinaceum)
  3. 1768Linné, Carl (1768) (as arsenicum cubicum)
  4. 1771Hill, John (1771) Fossils arranged according to their obvious characters. R. Baldwin, in Pater-Noster Row, 420 pgs. (as white arsenic)
  5. 1845Haidinger, Wilhelm (1845) Handbuch der bestimmenden Mineralogie, enthaltend die Terminologie, Systematik, Nomenklatur und Charakteristik der Naturgeschichte des Mineralreiches (1st ed.) Braumüller & Seidel, Vienna.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Arsenolite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/arsenolite-294},
  note      = {Accessed 2026-05-11}
}