Cryolithionite

Na3Al2(LiF4)3
IMA status
  • Approved
  • Grandfathered
IMA symbol
Cyln
Discovered
1904
Also known as
  • Cryolithioniet
  • Kryolithionite
  • Kryolthionit

Where it forms, where it's found

Type locality
Ivigtut Mine
  1. Ivigtut stock
  2. Arsuk Fjord
  3. Sermersooq
  4. Greenland

61.2061°, -48.1756°

4recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Transparency
Transparent
Colour
Colourless · white
Streak
White
Tenacity
brittle
Cleavage
Distinct/Good

On (011).

Fracture
Irregular/Uneven · Sub-Conchoidal
Density
2.77 g/cm³

Optical

Optical type
Isotropic
Isotropy testPPL ↔ XPL diagnostic
PPL intrinsic colour; no change on stage rotation
XPL extinct at every orientation

Crystallography

Crystal system
Isometric
Space group
#225
Cell parameters
a = 12.12 Å
Morphology

Crystals dodecahedral, modified by (112) (Urals). Artificial crystals cubic. Crystals to 17 cm (Ivigtut).

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
9FFluorineFluorine1218.998227.976
61.33%
11NaSodiumSodium322.99068.970
18.55%
13AlAluminiumAluminium226.98253.964
14.52%
3LiLithiumLithium36.94020.820
5.60%
Total371.730100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Cryolithioniet
  • Kryolithionite
  • Kryolthionit

In other languages

German
Kryolithionit
Italian
Criolitionite

Classification

Strunz
10th ed.

3.CB.05

  • 3HalidesClass
  • 3.CComplex halidesDivision
  • 3.CBNeso-aluminofluoridesGroup
  • 3.CB.05CryolithioniteSpecies
Dana
8th ed.

11.06.04.01

  • 11Halide ComplexesClass
  • 11.06Aluminofluorides - Isolated OctahedraType
  • 11.06.04— unnamed intermediate level —Group
  • 11.06.04.01CryolithioniteSpecies
CIM

8.6.4

  • 8Halides - Fluorides, Chlorides, Bromides and Iodides; also Fluoborates and FluosilicatesClass
  • 8.6Halides of AlGroup
  • 8.6.4CryolithioniteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1904Ussing, N.V. (1904) Sur la cryolithionite, espèce minérale nouvelle. Oversigt over det Kongelige Danske Videnskabernes Selskabs Forhandlinger 1904: 2-12.
  2. 1913Bøggild (1913) Zeitschrift für Kristallographie, Mineralogie und Petrographie, Leipzig: 51: 600.
  3. 1930Menzer (1930) Zeitschrift für Kristallographie, Mineralogie und Petrographie, Leipzig: 75: 265.
  4. 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
  5. 1971Geller, S. (1971) Refinement of the crystal structure of cryolithionite, {Na3}[Al2](Li3)F12. American Mineralogist, 56 (1-2) 18-23
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Cryolithionite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/cryolithionite-1162},
  note      = {Accessed 2026-05-11}
}