Cualstibite

Cu2Al(OH)6[Sb(OH)6]
IMA status
  • Approved
IMA symbol
Casb
Discovered
1984
Also known as
  • Cualstibiet
  • IMA1983-068

Where it forms, where it's found

Geological setting

A secondary mineral from oxidation of a hydrothermal, polymetallic barite–fluorite deposit.

Type locality
Clara Mine
  1. Oberwolfach
  2. Ortenaukreis
  3. Freiburg Region
  4. Baden-Württemberg
  5. Germany

48.3797°, 8.2289°

11recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Blue-green
Streak
Bluish-white
Cleavage
None Observed

No distinct cleavage

Fracture
Conchoidal

Optical

Optical type
Uniaxial (-)
Refractive index
1.644 – 1.672
Surface relief
High
Principal indices
nω 1.672 · nε 1.644
Pleochroism

E +/- colorless, O light blue-green.

UV response
Not florescent
Notes

Data for 1T polytype.

Michel-Lévy diagramhighlighted lineδ = 0.0280
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]280 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation280 nm
Order1st order
XPL colour

Crystallography

Crystal system
Trigonal
Space group
#79
Cell parameters
a = 9.15(2) Å · c = 9.745(2) Å
Unit cell volume
706.6 ų
Z
3
Morphology

Short prismatic along [001] (data for 1T polytype).

Twinning

Twin axis [110].

Type-locality form

Columnar, trigonal crystals, up to 0.05 mm long, in voids; crustiform on barite and fluorite; radial aggregates; pseudomorphs after an unknown mineral; and massive.

Comment

Data for 1T polytype. Structure solved from twinned crystal.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1215.999191.988
40.01%
29CuCopperCopper263.546127.092
26.48%
51SbAntimonyAntimony1121.760121.760
25.37%
13AlAluminiumAluminium126.98226.982
5.62%
1HHydrogenHydrogen121.00812.096
2.52%
Total479.918100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Cualstibiet
  • IMA1983-068

In other languages

German
Cualstibit · IMA 1983-068
Italian
Cualstibite

Classification

Strunz
10th ed.

4.FB.10

  • 4OxidesClass
  • 4.FHydroxides (without V or U)Division
  • 4.FBHydroxides with OH, without H2O; insular octahedraGroup
  • 4.FB.10CualstibiteSpecies
Dana
8th ed.

44.03.10.01

  • 44AntimonatesClass
  • 44.03MiscellaneousType
  • 44.03.10Cualstibite GroupGroup
  • 44.03.10.01CualstibiteSpecies
CIM

24.1.4

  • 24Antimonates and AntimonitesClass
  • 24.1Antimonates and antimonites of Na, Cu or AgGroup
  • 24.1.4CualstibiteSpecies

Group, growth & confusion

In the same group
2 members

Literature, links & citation

Citations
  1. 1984Walenta, K. (1984): Cualstibit, ein neues Sekundärmineral aus der Grube Clara im mittleren Schwarzwald (BRD). Chemie der Erde 43, 255-260. (in German)
  2. 1985Dunn, Pete J., Ferraiolo, James A., Fleischer, Michael, Gobel, Volker, Grice, Joel D., Langley, Richard H., Shigley, James E., Vanko, David A., Zilczer, Janet A. (1985) New mineral names. American Mineralogist, 70 (11-12) 1329-1335
  3. 2005(2005) Cualstibite. Handbook of Mineralogy. Mineralogical Society of America
  4. 2007Bonaccorsi, E., Merlino, S., Orlandi, P. (2007) Zincalstibite, a new mineral, and cualstibite: Crystal chemical and structural relationships. American Mineralogist, 92 (1) 198-203 doi:10.2138/am.2007.2240 DOI: 10.2138/am.2007.2240
  5. 2012Mills, S. J.; Christy, A. G.; Génin, J.-M. R.; Kameda, T.; Colombo, F. (2012) Nomenclature of the hydrotalcite supergroup: natural layered double hydroxides. Mineralogical Magazine, 76 (5). 1289-1336 doi:10.1180/minmag.2012.076.5.10DOI: 10.1180/minmag.2012.076.5.10
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Cualstibite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/cualstibite-1167},
  note      = {Accessed 2026-05-11}
}