Zincalstibite

Zn2Al(OH)6[Sb(OH)6]
IMA status
  • Approved
IMA symbol
Zas
IMA approved
1998
Also known as
  • IMA1998-033
  • Zincalstibiet
  • Zinkalstibit

Where it forms, where it's found

Geological setting

Marble quarry. An alteration product of different sulfides by Al-rich hydrothermal fluids.

Type locality
Fantiscritti
  1. Miseglie quarrying basin (Miseglia-Fantiscritti quarrying basin
  2. Fantiscritti quarrying basin)
  3. Carrara
  4. Massa-Carrara Province
  5. Tuscany
  6. Italy

44.0900°, 10.1333°

6recorded occurrences
Source · OpenStreetMap

Physical

Transparency
Transparent
Colour
Colourless
Streak
White
Cleavage

(001)

Optical

Optical type
Uniaxial (-)
Refractive index
1.626 – 1.647
Surface relief
Moderate
Principal indices
nω 1.647 · nε 1.626
Pleochroism
Non-pleochroic
Notes

optical data from Mills et al. (2012)

Michel-Lévy diagramhighlighted lineδ = 0.0210
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]210 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation210 nm
Order1st order
XPL colour

Crystallography

Crystal system
Trigonal
Space group
#79
Cell parameters
a = 5.327(8) Å · c = 9.792(2) Å
Unit cell volume
240.64 ų
Z
1
Morphology

Trigonal prisms with forms (110) and (001) and elongated on [001].

Twinning

Twin axis [210].

Type-locality form

Tiny colourless trigonal prisms.

Comment

Structure solved from twinned crystal.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1215.999191.988
39.70%
30ZnZincZinc265.380130.760
27.04%
51SbAntimonyAntimony1121.760121.760
25.18%
13AlAluminiumAluminium126.98226.982
5.58%
1HHydrogenHydrogen121.00812.096
2.50%
Total483.586100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1998-033
  • Zincalstibiet
  • Zinkalstibit

In other languages

German
IMA 1998-033 · Zincalstibit
Italian
Zincalstibite

Classification

Strunz
10th ed.

4.FB.10

  • 4OxidesClass
  • 4.FHydroxides (without V or U)Division
  • 4.FBHydroxides with OH, without H2O; insular octahedraGroup
  • 4.FB.10ZincalstibiteSpecies

Group, growth & confusion

In the same group
2 members

Literature, links & citation

Citations
  1. 2004Orlandi, P. (2004) Rivista Mineralogica Italiana, 1/2004, 24-27.
  2. 2007Bonaccorsi, E., Merlino, S., Orlandi, P. (2007) Zincalstibite, a new mineral, and cualstibite: Crystal chemical and structural relationships. American Mineralogist, 92 (1) 198-203 doi:10.2138/am.2007.2240 DOI: 10.2138/am.2007.2240
  3. 2012Mills, S. J., Christy, A. G., Kampf, A. R., Housley, R. M., Favreau, G., Boulliard, J.-C., Bourgoin, V. (2012) Zincalstibite-9R: the first nine-layer polytype with the layered double hydroxide structure-type. Mineralogical Magazine, 76 (5) 1337-1345 doi:10.1180/minmag.2012.076.5.01DOI: 10.1180/minmag.2012.076.5.01
  4. 2012Mills, S. J.; Christy, A. G.; Génin, J.-M. R.; Kameda, T.; Colombo, F. (2012) Nomenclature of the hydrotalcite supergroup: natural layered double hydroxides. Mineralogical Magazine, 76 (5). 1289-1336 doi:10.1180/minmag.2012.076.5.10DOI: 10.1180/minmag.2012.076.5.10
  5. 2021(2021) Zincalstibite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Zincalstibite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/zincalstibite-7055},
  note      = {Accessed 2026-05-11}
}