Diaoyudaoite

NaAl11O17
IMA status
  • Approved
IMA symbol
Dyd
Discovered
1985
IMA approved
1985
Also known as
  • Diaoyudaoiet
  • IMA1985-005

Where it forms, where it's found

Geological setting

Seafloor mud.

Slag piles, waste dumps, and sites of illegal toxic waste dumping.

Type locality
Okinawa Trough
  1. Senkaku Islands (Diaoyudao Islands
  2. Diaoyutai Islands)
  3. Ishigaki City
  4. Okinawa Prefecture
  5. Japan

25.4333°, 123.3667°

6recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789107.5 – 8/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Transparency
Transparent
Colour
Colourless · light green
Cleavage
Distinct/Good

One direction, good.

Fracture
Conchoidal
Density
3.30 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.663 – 1.6876
Surface relief
High
Principal indices
nω 1.6876 · nε 1.663
Michel-Lévy diagramhighlighted lineδ = 0.0246
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]246 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation246 nm
Order1st order
XPL colour

Crystallography

Crystal system
Hexagonal
Space group
P63/mmc
Cell parameters
a = 5.602(1) Å · c = 22.625(5) Å
Z
2
Type-locality form

Crystals thin tabular, to 0.5 mm.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
13AlAluminiumAluminium1126.982296.802
50.15%
8OOxygenOxygen1715.999271.983
45.96%
11NaSodiumSodium122.99022.990
3.89%
Total591.775100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Cr

Synonyms

  • Diaoyudaoiet
  • IMA1985-005

In other languages

German
Diaoyudaoit · IMA 1985-005
Spanish
Diaoyudaoíta
Italian
Diaoyudaoite

Classification

Strunz
10th ed.

4.CC.45

  • 4OxidesClass
  • 4.CMetal: Oxygen = 2: 3,3: 5, and similarDivision
  • 4.CCWith large and medium-sized cationsGroup
  • 4.CC.45DiaoyudaoiteSpecies
Dana
8th ed.

07.11.12.01

  • 07Multiple OxidesClass
  • 07.11MiscellaneousType
  • 07.11.12— unnamed intermediate level —Group
  • 07.11.12.01DiaoyudaoiteSpecies
CIM

7.2.2

  • 7Oxides and HydroxidesClass
  • 7.2Oxides of the alkali metalsGroup
  • 7.2.2DiaoyudaoiteSpecies

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1986Shen Shunxi, Chen Lirong, Li Anchun, Dong Tailu, Huang Qiuhuo, and Xu Wenqiang (1986): Diaoyudaoite - A new mineral. Acta Mineralogica Sinica 6(3), 224-227 (in Chinese with English abstract). - American Mineralogist (1987), 75, 240 (abstract).
  2. 1986Shen Shunxi, Chen Lirong, Li Anchun, Dong Tailu, Huang Qiuhuo, and Xu Wenqiang (1986): Diaoyudaoite - A new mineral. Acta Mineralogica Sinica 6(3), 224-227 (in Chinese with English abstract).
  3. 1992Zhu, Naijue; Guo, Fang; Li, Yan; Shen, Shunxi; Chen, Lirong; Li, Anchun. (1992): Study on crystal structure of diaoyudaoite. Huaxue Xuebao 50, 527-32. (in Chinese).
  4. 1998Ye, Ying; Shen, Zhongyue; Shimizu, Masaaki; Shimazaki, Hidehiko (1998): Comparison between metallurgical byproduct beta-NaAl11O17 and diaoyudaoite and discussion on the possible source of diaoyudaoite. Kuangwu Xuebao 18, 97-100. (in Chinese).
  5. 2005(2005) Diaoyudaoite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Diaoyudaoite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/diaoyudaoite-1283},
  note      = {Accessed 2026-05-11}
}