Doyleite

Al(OH)3
IMA status
  • Approved
IMA symbol
Doy
Discovered
1985
Also known as
  • Doyleiet
  • IMA1980-041

Where it forms, where it's found

Geological setting

In albitite veins in nepheline syenite (MSH) and in silicocarbonatite sills (Francon).

Type locality
Francon quarry
  1. Montréal
  2. Québec
  3. Canada

45.5679°, -73.6060°

16recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5 – 3/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous · Pearly
Transparency
Transparent · Translucent · Opaque
Colour
White · creamy-white · bluish-white
Streak
White
Tenacity
flexible
Cleavage
Perfect

Perfect on (010), fair on (100).

Density
2.48 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 77° · 2V calc = 78°
Refractive index
1.545 – 1.566
Surface relief
Moderate
Principal indices
nα 1.545 · nβ 1.553 · nγ 1.566
Dispersion
None. Type description gives strong, r > v.
UV response
Not fluorescent.
Michel-Lévy diagramhighlighted lineδ = 0.0210
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]210 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation210 nm
Order1st order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 5.00 Å · b = 5.17 Å · c = 4.98 Å
Cell angles
α = 97.5 ° · β = 118.6 ° · γ = 104.74 °
Ratio a:b:c
1 : 1.034 : 0.996
Morphology

Type material: Crystals are tabular on (010), showing forms (010), (101), (101), and occasionally (100) and (001).

Type-locality form

Rosettes of platy crystals (MSH), and as pulverulent to compact globules, botryoidal and smooth porcelain like crusts and sheets (Francon).

Comment

Space group P-1 (Clark et al., 1998).

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen315.99947.997
61.53%
13AlAluminiumAluminium126.98226.982
34.59%
1HHydrogenHydrogen31.0083.024
3.88%
Total78.003100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Doyleiet
  • IMA1980-041

In other languages

French
doyleite
German
Doyleit · IMA 1980-041
Spanish
Doyleíta
Italian
Doyleite
Chinese
督三水铝石

Classification

Strunz
10th ed.

4.FE.10

  • 4OxidesClass
  • 4.FHydroxides (without V or U)Division
  • 4.FEHydroxides with OH, without H2O; sheets of edge-sharing octahedraGroup
  • 4.FE.10DoyleiteSpecies
Dana
8th ed.

06.03.04.01

  • 06Hydroxides and Oxides Containing HydroxylClass
  • 06.03X(OH)3Type
  • 06.03.04— unnamed intermediate level —Group
  • 06.03.04.01DoyleiteSpecies
CIM

7.6.7

  • 7Oxides and HydroxidesClass
  • 7.6Oxides of AlGroup
  • 7.6.7DoyleiteSpecies

Group, growth & confusion

Commonly confused with
3 minerals

Literature, links & citation

Citations
  1. 1985Chao, G. Y., Baker, J., Sabina, A. P., Roberts, A. C. (1985) Doyleite, a new polymorph of Al(OH)3, and its relationship to bayerite, gibbsite and nordstrandite. The Canadian Mineralogist, 23 (1) 21-28
  2. 1986Hawthorne, F.C., Dunn, P.J., Grice, J.D., Puziewicz, J., Shigley, J.E. (1986) New mineral names. American Mineralogist: 71: 845-847.
  3. 1998Jambor, John L.; Kovalenker, Vladimir A.; Roberts, Andrew C. (1998) New mineral names. American Mineralogist, 83. 1117-1121
  4. 1998Clark, G. R., Rodgers, K. A., Henderson, G. S. (1998) The crystal chemistry of doyleite, Al(OH)3. Zeitschrift für Kristallographie, 213 (2). 96-100 doi:10.1524/zkri.1998.213.2.96 DOI: 10.1524/zkri.1998.213.2.96
  5. 2005(2005) Doyleite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Doyleite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/doyleite-1316},
  note      = {Accessed 2026-05-11}
}