Dufrénoysite

Pb2As2S5
IMA status
  • Approved
  • Grandfathered
IMA symbol
Duf
Also known as
  • Arsenomelan
  • Bleiarsenit
  • Dufrénoysiet
  • +16 more

Where it forms, where it's found

Geological setting

Moderate to low temperature hydrothermal deposits.

Type locality
Lengenbach Quarry
  1. Fäld
  2. Binn
  3. Goms
  4. Valais
  5. Switzerland

46.3653°, 8.2205°

32recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Metallic
Transparency
Opaque
Colour
Dark lead-grey · dark red-brown (transmitted light)
Streak
Reddish brown, chocolate brown
Tenacity
brittle
Cleavage
Perfect

(010) perfect

Fracture
Conchoidal
Density
5.50 g/cm³

Optical

Pleochroism
Weak

Very weak.

Optical colour
White
Anisotropism
Strong in brown-violet and deep green.
Internal reflections
Deep red at times.
Tropism
Anisotropic
Reflectance R%
(39.5,42.1) 400, (39.0,41.7) 420, (38.5,41.1) 440, (38.1,40.6) 460, (37.8,40.2) 480, (37.4,39.7) 500, (37.0,39.0) 520, (36.6,38.4) 540, (36.1,37.6) 560, (35.6,36.9) 580, (34.9,36.2) 600, (34.2,35.4) 620, (33.3,34.6) 640, (32.5,33.7) 660, (31.7,33.0) 680, (31.0,32.4) 700
Reflected-light panel
35.8 %anisotropic · dual curve
Specimen sRGB 209, 151, 86
White reference100 % reflector under same lamp
R₁ R₂
Mode
Anisotropism
Strong in brown-violet and deep green.
Reflected colour
White
Internal reflections
Deep red at times.

Crystallography

Crystal system
Monoclinic
Space group
#9
Cell parameters
a = 7.90 Å · b = 25.74 Å · c = 8.37 Å
Cell angles
β = 90.35 °
Ratio a:b:c
1 : 3.258 : 1.059
Z
2
Morphology

Tabular (010) and somewhat elongated [100]; also elongated [010] and striated [100] to 3 cm.

Twinning

On (001).

Type-locality form

Well-formed metallic crystals.

Comment

The X-ray powder pattern closely resembles that of veenite.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
82PbLeadLead2207.200414.400
57.20%
16SSulfurSulfur532.060160.300
22.12%
33AsArsenicArsenic274.922149.844
20.68%
Total724.544100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Arsenomelan
  • Bleiarsenit
  • Dufrénoysiet
  • Dufrenoysite (of Damour)
  • Gothardit
  • Gothardita
  • Gothardite
  • Gotthardit
  • Gotthardita
  • Gotthardite
  • Gotthardtit
  • Gotthardtita
  • Gotthardtite
  • Plumbobinnit
  • Plumbobinnita
  • Plumbobinnite
  • Rathite-1a
  • Scleroclase (of Peterson and Wherry)
  • Scleroklas

In other languages

French
Dufrénoysite · Scléroclase
German
Dufrénoysit
Spanish
Dufrénoysita · Gothardita · Plumbobinnita
Italian
Dufrénoysite

Classification

Strunz
10th ed.

2.HC.05d

  • 2Sulfides and SulfosaltsClass
  • 2.HSulfosalts of SnS archetypeDivision
  • 2.HCWith only PbGroup
  • 2.HC.05dDufrénoysiteSpecies
Dana
8th ed.

03.05.09.03

  • 03SulfosaltsClass
  • 03.052.5 < ø < 3Type
  • 03.05.09Cosalite GroupGroup
  • 03.05.09.03DufrénoysiteSpecies
CIM

5.6.2

  • 5Sulphosalts - Sulpharsenites and Sulphobismuthites (those containing Sn, Ge,or V are in Section 6)Class
  • 5.6Sulpharsenites etc. of Pb aloneGroup
  • 5.6.2DufrénoysiteSpecies

Group, growth & confusion

Often grow together
1 mineral

Literature, links & citation

Citations
  1. 1845Damour, A.A. (1845) Sur le sulfo-arséniure de plomb du mont Saint-Gothard (Nouvelle espèce minérale). Annales de Chimie et de Physique: 14: 379-383. (in French)
  2. 1847Rammelsberg (1847) 229, 256. (as Gotthardit)
  3. 1855Des Cloizeaux, A.L.O. (1855) Sur les formes cristallines de la dufrenoysite. Annales des Mines: 8: 389-398.
  4. 1855von Waltershausen, W.S. (1855) Ein Beitrag zur naheren Kenntniss des Dolomits in den Walliser Alpen. Annalen der Physik und Chemie (Poggendorf): 94: 115-141.
  5. 1856Heusser, C. (1856) Ueber den Dufrenoysit, Binnit und Adular des Binnenthales. Annalen der Physik und Chemie: 97: 115-129.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Dufrénoysite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/dufrenoysite-1324},
  note      = {Accessed 2026-05-11}
}