Erythrosiderite

K2Fe3+Cl5 · H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Esd
Discovered
1872
Also known as
  • Erythrosideriet
  • Erythrosiderita

Where it forms, where it's found

Geological setting

Active volcanic fumaroles.

Type locality
Mount Vesuvius
  1. Metropolitan City of Naples
  2. Campania
  3. Italy
10recorded occurrences
Source · OpenStreetMap

Physical

Colour
Ruby-red to red · brownish red · brown-red or yellowish in transmitted light.
Cleavage
Perfect

On (201) and (011).

Density
2.372 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 62° · 2V calc = 82°
Refractive index
1.715 – 1.8
Surface relief
High
Principal indices
nα 1.715 · nβ 1.75 · nγ 1.8
Dispersion
strong
Michel-Lévy diagramhighlighted lineδ = 0.0850
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]850 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation850 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
#71
Cell parameters
a = 9.7 Å · b = 13.58 Å · c = 7.01 Å
Ratio a:b:c
1 : 1.400 : 0.723
Morphology

Crystals somewhat tabular (100).

Twinning

On [21_1] and [20_1] (artificial material).

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
17ClChlorineChlorine535.450177.250
53.82%
19KPotassiumPotassium239.09878.196
23.75%
26FeIronIron155.84555.845
16.96%
8OOxygenOxygen115.99915.999
4.86%
1HHydrogenHydrogen21.0082.016
0.61%
Total329.306100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Al

Synonyms

  • Erythrosideriet
  • Erythrosiderita

In other languages

German
Erythrosiderit
Spanish
Eritrosiderita
Italian
Eritrosiderite

Classification

Strunz
10th ed.

3.CJ.10

  • 3HalidesClass
  • 3.CComplex halidesDivision
  • 3.CJWith MX6 complexes; M = Fe, Mn, CuGroup
  • 3.CJ.10ErythrosideriteSpecies
Dana
8th ed.

11.04.01.01

  • 11Halide ComplexesClass
  • 11.04AmBX5·xH2OType
  • 11.04.01— unnamed intermediate level —Group
  • 11.04.01.01ErythrosideriteSpecies
CIM

8.11.5

  • 8Halides - Fluorides, Chlorides, Bromides and Iodides; also Fluoborates and FluosilicatesClass
  • 8.11Halides of Fe and NiGroup
  • 8.11.5ErythrosideriteSpecies

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. National Bureau of Standards (U.S.) Monograph 25, section 14: 27.
  2. 1872Scacchi, A. (1872) Notizie preliminari di alcune specie mineralogiche rinvenute nel Vesuvio dopo l'incendio di aprile 1872. Rendiconto dell'Accademia delle Scienze Fisiche e Matematiche (sezione della Societa reale di Napoli): 11: 210-213.
  3. 1874Scacchi, A. (1874) Contribuzioni mineralogiche per servire all Storia dell’ Incendio Vesuviano, del mese di Aprile, Part 2: 42.
  4. 1905Gossner (1905) Zeitschrift für Kristallographie, Mineralogie und Petrographie, Leipzig: 40: 73 (artif. mat.)
  5. 1934Larsen, E.S.; Berman, H. (1934) The microscopic determination of the nonopaque minerals. Bulletin of the US Geological Survey Vol. 848. US Geological Survey p.1-266. doi:10.3133/b848 DOI: 10.3133/b848
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Erythrosiderite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/erythrosiderite-1408},
  note      = {Accessed 2026-05-11}
}