Kremersite

(NH4)2Fe3+Cl5 · H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Km
Discovered
1853
Also known as
  • Eisenchlorid mit Chlorkalium
  • Kopeiskite
  • Kopeyskite

Where it forms, where it's found

Geological setting

Active volcanic fumaroles.

Type locality
Mount Vesuvius
  1. Metropolitan City of Naples
  2. Campania
  3. Italy
12recorded occurrences
Source · OpenStreetMap

Physical

Transparency
Translucent
Colour
Ruby-red to red · brownish red
Cleavage
Perfect

On (211) and (011).

Density
2.175 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 70° · 2V calc = 82°
Refractive index
1.733 – 1.807
Surface relief
High
Principal indices
nα 1.733 · nβ 1.763 · nγ 1.807
Dispersion
r > v or r < v
Michel-Lévy diagramhighlighted lineδ = 0.0740
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]740 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation740 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
Pnma
Cell parameters
a = 13.78 Å · b = 9.85 Å · c = 7.09 Å
Ratio a:b:c
1 : 0.715 : 0.515
Z
4
Morphology

Crystals pseudooctahedral with (011) and (210) in equal development.

Twinning

On [21_1] and [20_1] (artificial material)

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
17ClChlorineChlorine535.450177.250
61.72%
26FeIronIron155.84555.845
19.45%
7NNitrogenNitrogen214.00728.014
9.75%
8OOxygenOxygen115.99915.999
5.57%
1HHydrogenHydrogen101.00810.080
3.51%
Total287.188100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Eisenchlorid mit Chlorkalium
  • Kopeiskite
  • Kopeyskite

In other languages

French
Kremersite
German
Kremersit
Italian
Kremersite

Classification

Strunz
10th ed.

3.CJ.10

  • 3HalidesClass
  • 3.CComplex halidesDivision
  • 3.CJWith MX6 complexes; M = Fe, Mn, CuGroup
  • 3.CJ.10KremersiteSpecies
Dana
8th ed.

11.04.01.02

  • 11Halide ComplexesClass
  • 11.04AmBX5·xH2OType
  • 11.04.01— unnamed intermediate level —Group
  • 11.04.01.02KremersiteSpecies
CIM

8.11.7

  • 8Halides - Fluorides, Chlorides, Bromides and Iodides; also Fluoborates and FluosilicatesClass
  • 8.11Halides of Fe and NiGroup
  • 8.11.7KremersiteSpecies

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1851Kremers P (1851) Ueber die aschenbestandtheile und die producte der trocknen destillation bei braun- und steinkohlen. Ueber das natürliche vorkommen des doppelsaizes von eisenchlorid mit den chloralkalien. Annalen der Physik und Chemie 84, 67-80
  2. 1853Kenngott A (1853) IV. Ordnung: Salze. Eisenchlorid mit chloralkalien. in Uebersicht der Resultate Mineralogischer Forschungen in den Jahren 1850 und 1851, K K Hof- und Staatsdruckerei (Wien) 24-24
  3. 1903Johnson (1903) Neues Jahrbuch für Mineralogie, Geologie und Paleontologie, Heidelberg, Stuttgart: II: 93 (artif. mat.).
  4. 1907Lacroix (1907) Bulletin de la Société française de Minéralogie: 30: 253.
  5. 1908Lacroix (1908) Comptes rendu de l’Académie des sciences de Paris: 147: 162.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Kremersite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/kremersite-2273},
  note      = {Accessed 2026-05-11}
}