Fanfaniite

Ca4Mn2+Al4(PO4)6(OH)4 · 12H2O
IMA status
  • Approved
IMA symbol
Ffa
IMA approved
2018
Also known as
  • Fanfaniiet
  • IMA2018-053

Where it forms, where it's found

Geological setting

oxidation of pegmatite phosphates.

Type locality
Foote Lithium Co. Mine
  1. Kings Mountain
  2. Cleveland County
  3. North Carolina
  4. USA

35.2111°, -81.3556°

4recorded occurrences
Source · OpenStreetMap

Physical

Transparency
Transparent
Colour
colorless

Optical

Optical type
Biaxial (-) · 2V measured = 57°
Refractive index
1.573 – 1.585
Surface relief
Moderate
Principal indices
nα 1.573 · nβ 1.582 · nγ 1.585
Pleochroism
Not Visible
Michel-Lévy diagramhighlighted lineδ = 0.0120
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]120 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation120 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/c
Cell parameters
a = 10.055(2) Å · b = 24.132(5) Å · c = 6.2590(10) Å
Cell angles
β = 91.35(3) °
Ratio a:b:c
1 : 2.400 : 0.622
Type-locality form

Radial aggregates up to 0.5 mm in diameter of colourless, transparent, thin blades, associated with whiteite-(CaMnMn). At Hagendorf-Süd, the mineral occurs as isolated very thin laths on the surface of fibrous spheroids of kayrobertsonite.

Comment

updated from specimen from Hühnerkobel pegmatite, may be triclinic

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen4015.999639.960
54.36%
15PPhosphorusPhosphorus630.974185.844
15.79%
20CaCalciumCalcium440.078160.312
13.62%
13AlAluminiumAluminium426.982107.928
9.17%
25MnManganeseManganese154.93854.938
4.66%
1HHydrogenHydrogen281.00828.224
2.40%
Total1177.206100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Fanfaniiet
  • IMA2018-053

In other languages

German
Fanfaniit · IMA 2018-053

Classification

Strunz
10th ed.

8.DH.25

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DHWith large and medium-sized cations, (OH, etc.):RO4 < 1:1Group
  • 8.DH.25FanfaniiteSpecies

Group, growth & confusion

In the same group
2 members

Literature, links & citation

Citations
  1. www.mindat.org (n.d.) https://www.mindat.org/mesg-14-447979.html
  2. 2018Hålenius, U., Hatert, F., Pasero, M., Mills, S. J. (2018) CNMNC Newsletter 45, New minerals and nomenclature modifications approved in 2018. Mineralogical Magazine, 82 (5) 1225-1232 doi:10.1180/mgm.2018.160DOI: 10.1180/mgm.2018.160
  3. 2019Roattino, T., Meisser, N., Iob, S., Berbain, C. (2019): Sur la fanfaniite de Font Andreu, Argèles-sur-Mer (Pyrénées-Orientales). Cahier des Micromonteurs, 2/2019, 24-27.
  4. 2019Grey, Ian E., Kampf, Anthony R., Smith, Jason B., MacRae, Colin M., Keck, Erich (2019) Fanfaniite, Ca4Mn2+Al4(PO4)6(OH,F)4·12H2O, a new mineral with a montgomeryite-type structure. European Journal of Mineralogy, 31 (3) 647-652 doi:10.1127/ejm/2019/0031-2857 DOI: 10.1127/ejm/2019/0031-2857
  5. 2026Grey, Ian E.; Bird, Stephanie; MacRae, Colin M.; Rewitzer, Christian; Hochleitner, Rupert (2026) Structural ordering in calcioferrite-group minerals. Refinement of the crystal structure of fanfaniite from the Hühnerkobel pegmatite, Bavaria. Mineralogical Magazine, 90 (1). 181-191 doi:10.1180/mgm.2025.10116DOI: 10.1180/mgm.2025.10116
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Fanfaniite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/fanfaniite-53148},
  note      = {Accessed 2026-05-11}
}