Ferrinatrite

Na3Fe3+(SO4)3 · 3H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Fnat
Discovered
1889
Also known as
  • Ferrinatriet
  • Ferronatrit
  • Ferronatrita
  • +3 more

Where it forms, where it's found

Geological setting

Oxidation zone of iron sulfides in an arid region. Rarely in fumaroles.

Type locality
La Compañia Mine
  1. Sierra Gorda
  2. Antofagasta Province
  3. Antofagasta
  4. Chile

-22.9408°, -69.3436°

23recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Colourless · grayish white · pale green · bluish green · amethystine · colourless in transmitted light.
Streak
White
Tenacity
brittle
Cleavage
Perfect

Perfect on (1010) Less perfect (1120)

Fracture
Splintery
Density
2.55 g/cm³

Optical

Optical type
Uniaxial (+)
Refractive index
1.556 – 1.613
Surface relief
Moderate
Principal indices
nω 1.556 – 1.558 · nε 1.61 – 1.613
Notes

Colorless in thin section.

Michel-Lévy diagramhighlighted lineδ = 0.0545
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]545 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation545 nm
Order1st order
XPL colour

Crystallography

Crystal system
Trigonal
Space group
#79
Cell parameters
a = 15.553(2) Å · c = 8.6616(17) Å
Z
6
Morphology

Crystals short prismatic [0001]. Isolated individuals or stellate groups; fibrous aggregates or cleavable masses; cryptocrystalline.

Type-locality form

Stellate groups of crystals forming nearly spherical nodules. Generally similar to pale wavellite in appearance.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1515.999239.985
51.39%
16SSulfurSulfur332.06096.180
20.59%
11NaSodiumSodium322.99068.970
14.77%
26FeIronIron155.84555.845
11.96%
1HHydrogenHydrogen61.0086.048
1.29%
Total467.028100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Ferrinatriet
  • Ferronatrit
  • Ferronatrita
  • Ferronatrite
  • Gordaite (of Frenzel)
  • Leucoglaucite

In other languages

German
Ferrinatrit
Italian
Ferrinatrite

Classification

Strunz
10th ed.

7.CC.35

  • 7SulfatesClass
  • 7.CSulfates (selenates, etc.) without additional anions, with H2ODivision
  • 7.CCWith medium-sized and large cationsGroup
  • 7.CC.35FerrinatriteSpecies
Dana
8th ed.

29.04.04.01

  • 29Hydrated Acid and Normal SulfatesClass
  • 29.04AmBn(XO4)p·xH2O, with (m+n):p < 3:2 and > 1:1Type
  • 29.04.04— unnamed intermediate level —Group
  • 29.04.04.01FerrinatriteSpecies
CIM

25.11.4

  • 25SulphatesClass
  • 25.11Sulphates of Fe and other metalsGroup
  • 25.11.4FerrinatriteSpecies

Group, growth & confusion

Often grow together
3 minerals

Literature, links & citation

Citations
  1. Handbook of Mineralogy: Vol V: 223.
  2. 1889Mackintosh, J.B. (1889) Notes on some native iron sulphates from Chili. American Journal of Science: 38: 242-245 (244). (as ferronatrite)
  3. 1890Frenzel (1890) Mineralogische und petrographische Mitteilungen, Vienna: 11: 218.
  4. 1890Genth, F.A., Penfield, S.L. (1890) Contributions to mineralogy, no 49. American Journal of Science: 40: 202.
  5. 1891Arzruni, A., Frenzel, A. (1891) Ueber den Ferronatrit. Zeitschrift für Krystallographie, 18 (1). 595-598 doi:10.1524/zkri.1891.18.1.595DOI: 10.1524/zkri.1891.18.1.595
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Ferrinatrite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/ferrinatrite-1497},
  note      = {Accessed 2026-05-11}
}