Ferrokësterite

Cu2FeSnS4
IMA status
  • Approved
IMA symbol
Fkës
Also known as
  • Ferrokësteriet
  • IMA1985-012

Where it forms, where it's found

Type locality
Cligga Mine
  1. Cligga Head
  2. Perranporth
  3. Perranzabuloe
  4. Cornwall
  5. England
  6. UK

50.3389°, -5.1778°

18recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Colour
Grey
Streak
Black

Optical

Optical colour
Medium gray
Anisotropism
Weak, shades of gray
Tropism
Anisotropic
Reflectance R%
(23.9,26.8) 470, (26.0,27.0) 546, (26.4,27.3) 589, (26.0,26.8) 650
Reflected-light panel
25.6 %anisotropic · dual curve
Specimen sRGB 187, 129, 66
White reference100 % reflector under same lamp
R₁ R₂
Mode
Anisotropism
Weak, shades of gray
Reflected colour
Medium gray

Crystallography

Crystal system
Tetragonal
Space group
#127
Cell parameters
a = 5.433(36) Å · c = 10.883(89) Å
Z
2
Comment

Space group by analogy to kesterite, but possibly I-42m (Bonazzi et al., 2003). Pseudocubic.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
16SSulfurSulfur432.060128.240
29.83%
29CuCopperCopper263.546127.092
29.56%
50SnTinTin1118.710118.710
27.62%
26FeIronIron155.84555.845
12.99%
Total429.887100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Ferrokësteriet
  • IMA1985-012

In other languages

German
Ferrokësterit · IMA 1985-012
Italian
Ferrokësterite

Classification

Strunz
10th ed.

2.CB.15a

  • 2Sulfides and SulfosaltsClass
  • 2.CMetal Sulfides, M: S = 1: 1 (and similar)Division
  • 2.CBWith Zn, Fe, Cu, Ag, etc.Group
  • 2.CB.15aFerrokësteriteSpecies
Dana
8th ed.

02.09.02.10

  • 02SulfidesClass
  • 02.09AmBnXp, with (m+n):p = 1:1Type
  • 02.09.02Stannite Group (Tetragonal: I-42m) A2BCS typeGroup
  • 02.09.02.10FerrokësteriteSpecies
CIM

6.1.10

  • 6Sulphosalts - Sulphostannates, Sulphogermanates,Sulpharsenates, Sulphantimonates, Sulphovanadates and SulphohalidesClass
  • 6.1Sulphostannates and other sulfides containing SnGroup
  • 6.1.10FerrokësteriteSpecies

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1989Kissin, S.A., Owens, D.R. (1989) The relatives of stannite in the light of new data. The Canadian Mineralogist, 27 (4) Mineralogical Association of Canada. 673-688
  2. 1990Bernardini, Gian Piero, Bonazzi, Paola, Corazza, Marcello, Corsini, Fernando, Mazzetti, Giuseppe, Poggi, Luisa, Tanelli, Giuseppe (1990) New data on the Cu2FeSnS4-Cu2ZnSnS4 pseudobinary system at 750° and 550 °C. European Journal of Mineralogy, 2 (2) 219-226 doi:10.1127/ejm/2/2/0219DOI: 10.1127/ejm/2/2/0219
  3. 2003Bonazzi, P., Bindi, L., Bernardini, G. P., Menchetti, S. (2003) A model for the mechanism of incorporation of Cu, Fe and Zn in the stannite-kësterite series, Cu2FeSnS4-Cu2ZnSnS4. The Canadian Mineralogist, 41 (3) 639-647 doi:10.2113/gscanmin.41.3.639 DOI: 10.2113/gscanmin.41.3.639
  4. 2005(2005) Ferrokësterite. Handbook of Mineralogy. Mineralogical Society of America
  5. 2005Di Benedetto, F.; Bernardini, G. P.; Borrini, D.; Lottermoser, W.; Tippelt, G.; Amthauer, G. (2005) 57Fe- and 119Sn-Mössbauer study on stannite (Cu2FeSnS4)-kesterite (Cu2ZnSnS4) solid solution. Physics and Chemistry of Minerals, 31 (10). 683-690 doi:10.1007/s00269-004-0430-yDOI: 10.1007/s00269-004-0430-y
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Ferrokësterite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/ferrokesterite-1522},
  note      = {Accessed 2026-05-11}
}