Stannite

Cu2FeSnS4
IMA status
  • Approved
  • Grandfathered
IMA symbol
Stn
Discovered
1797
Also known as
  • Bell-metal ore
  • Bolivianite (of Pauly)
  • Kassiterolamprit
  • +10 more

Where it forms, where it's found

Type locality
West Wheal Kitty (Wheal Rock)
  1. West Wheal Kitty group
  2. St Agnes
  3. Cornwall
  4. England
  5. UK

50.3123°, -5.2070°

708recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Metallic
Transparency
Opaque
Colour
Grey · black with an olive-green tint · tarnishes pale blue
Streak
Black
Cleavage
Poor/Indistinct

Indistinct on (110) (001)

Fracture
Irregular/Uneven
Density
4.3 g/cm³

Optical

Pleochroism
Weak

Indistinct in air, distinct in oil.

Optical colour
Gray with olive green tinge.
Anisotropism
Distinct violet - slate green
Tropism
Anisotropic
Reflectance R%
(21.4,22.2) 400, (23.5,24.7) 440, (26.2,27.0) 480, (27.7,28.3) 520, (27.6,28.3) 560, (27.0,27.6) 600, (26.6,27.1) 640, (26.5,27.0) 680, (26.7,27.1) 700
Reflected-light panel
25.9 %anisotropic · dual curve
Specimen sRGB 188, 133, 67
White reference100 % reflector under same lamp
R₁ R₂
Mode
Anisotropism
Distinct violet - slate green
Reflected colour
Gray with olive green tinge.

Crystallography

Crystal system
Tetragonal
Space group
#142
Cell parameters
a = 5.4432 Å · c = 10.7299 Å
Z
2
Morphology

Rarely as crystals

Twinning

Penetration twins on (102). Twin axis (112), Composition plane (112). Polysynthetic in polished section.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
16SSulfurSulfur432.060128.240
29.83%
29CuCopperCopper263.546127.092
29.56%
50SnTinTin1118.710118.710
27.62%
26FeIronIron155.84555.845
12.99%
Total429.887100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Ag
  • Zn
  • Cd
  • In

Synonyms

  • Bell-metal ore
  • Bolivianite (of Pauly)
  • Kassiterolamprit
  • Kassiterolamprita
  • Kassiterolamprite
  • Stanniet
  • Stannine
  • Stannite (of Dana)
  • Tin Pyrites
  • Tinnkis
  • Volfsonite
  • Zinnkies
  • Zinnkupferglanz

In other languages

French
Kassiterolamprite · Stannine · Stannite · Volfsonite
German
Stannit · Zinnkies
Spanish
Estannita
Italian
Stannite · Volfsonite
Japanese
黄錫鉱
Chinese
黝锡矿
Simplified Chinese
黝锡矿
Traditional Chinese
黝錫礦
Russian
Оловянный колчедан · Станнин · Станнит
Arabic
ستانيت

Classification

Strunz
10th ed.

2.CB.15a

  • 2Sulfides and SulfosaltsClass
  • 2.CMetal Sulfides, M: S = 1: 1 (and similar)Division
  • 2.CBWith Zn, Fe, Cu, Ag, etc.Group
  • 2.CB.15aStanniteSpecies
Dana
8th ed.

02.09.02.01

  • 02SulfidesClass
  • 02.09AmBnXp, with (m+n):p = 1:1Type
  • 02.09.02Stannite Group (Tetragonal: I-42m) A2BCS typeGroup
  • 02.09.02.01StanniteSpecies
CIM

6.1.6

  • 6Sulphosalts - Sulphostannates, Sulphogermanates,Sulpharsenates, Sulphantimonates, Sulphovanadates and SulphohalidesClass
  • 6.1Sulphostannates and other sulfides containing SnGroup
  • 6.1.6StanniteSpecies

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1797Klaproth, M. H. (1797) Untersuchung des Zinnkieses. In Beiträge zur chemischen Kenntniss der Mineralkörper Vol. 2. Rottmann, Berlin. p.257-264.
  2. 1810Klaproth, M. H. (1810) CCXIII. Chemische Untersuchung des Zinnkieses. In Beiträge zur chemischen Kenntniss der Mineralkörper Vol. 5. Rottmann. p.228-230.
  3. 1830Beudant, François-Sulpice (1830) Traité élémentaire de minéralogie. Deuxiéme Edition [Elementary Treatise on Mineralogy. Second Edition] (2nd ed.) Vol. 1 - Tome Premier [Volume One]. Chez Verdière.
  4. 1934Brockway, L. O. (1934) The Crystal Structure of Stannite, Cu2FeSnS4. Zeitschrift für Kristallographie - Crystalline Materials, 89 (1) 434-441 doi:10.1524/zkri.1934.89.1.434 DOI: 10.1524/zkri.1934.89.1.434
  5. 1944Palache, Charles, Berman, Harry, Frondel, Clifford (1944) The System of Mineralogy (7th ed.) Vol. 1 - Elements, Sulfides, Sulfosalts, Oxides. John Wiley and Sons, New York.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Stannite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/stannite-3747},
  note      = {Accessed 2026-05-11}
}