Ferrovalleriite

2[(Fe,Cu)S] · 1.53[(Fe,Al,Mg)(OH)2]
IMA status
  • Approved
IMA symbol
Fval
Discovered
2002
IMA approved
2011
Also known as
  • Ferrovalleriiet
  • IMA2011-068
  • UM1970-25-S:CuFeH
  • +1 more

Where it forms, where it's found

Type locality
Oktyabrsky Mine
  1. Talnakh Cu-Ni Deposit
  2. Norilsk-Talnakh Mining Region
  3. Taimyr Peninsula
  4. Taymyrskiy Autonomous Okrug
  5. Krasnoyarsk Krai
  6. Russia

69.5248°, 88.3401°

1recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789101/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Opaque
Colour
Dark bronze

It darkens, dulls, and is coated by goldish-brown or iridescent tarnish over time.

Streak
Black
Tenacity
flexible
Cleavage
Perfect

parallel to (001)

Fracture
Step-Like
Density
3.72 g/cm³

Optical

Pleochroism
Visible

yellowish to gray

Anisotropism
Strong bluish to yellowish beige
Bireflectance
moderate
Tropism
Anisotropic

Crystallography

Crystal system
Trigonal
Cell parameters
a = 3.792(2) Å · c = 34.06(3) Å
Z
3
Morphology

Hexagonal lamellar or tabular crystals (up to 2 mm across and 0.3 mm thick, which are slightly curved and divergent like an open book)

Type-locality form

holotype - (panel 5, belt 102) Two additional locations in mine were sampled for cotypes for XRPD and electron microprobe data.

Comment

Space group: R3¯ m, R3m or R32 - single crystals are curved and split

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
26FeIronIron3.5355.845197.133
37.99%
29CuCopperCopper263.546127.092
24.49%
16SSulfurSulfur232.06064.120
12.36%
8OOxygenOxygen3.0615.99948.957
9.44%
13AlAluminiumAluminium1.5326.98241.282
7.96%
12MgMagnesiumMagnesium1.5324.30537.187
7.17%
1HHydrogenHydrogen3.061.0083.084
0.59%
Total518.855100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Ferrovalleriiet
  • IMA2011-068
  • UM1970-25-S:CuFeH
  • Unnamed (Fe-analogue of Valleriite)

In other languages

German
Ferrovalleriit · IMA 2011-068
Italian
ferrovalleriite

Classification

Strunz
10th ed.

2.FD

  • 2Sulfides and SulfosaltsClass
  • 2.FSulfides of arsenic, alkalies; sulfides with halide, oxide, hydroxide, H2ODivision
  • 2.FDWith O, OH, H2OGroup
  • 2.FDFerrovalleriiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 2011Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2011) New minerals and nomenclature modifications approved in 2011. CNMNC Newsletter No 11. Mineralogical Magazine, 75 (6) 2887-2893 doi:10.1180/minmag.2011.075.6.2887 DOI: 10.1180/minmag.2011.075.6.2887
  2. 2013Pekov, I. V., Sereda, E. V., Yapaskurt, V. O., Polekhovsky, Yu. S., Britvin, S. N., Chukanov, N. V. (2013) Ferrovalleriite, 2(Fe,Cu)S · 1.5Fe(OH)2: Validation as a mineral species and new data. Geology of Ore Deposits, 55 (8) 637-647 doi:10.1134/s1075701513080102DOI: 10.1134/s1075701513080102
  3. 2014(2014) Ferrovalleriite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Ferrovalleriite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/ferrovalleriite-42850},
  note      = {Accessed 2026-05-11}
}