Valleriite

2[(Fe,Cu)S] · 1.53[(Mg,Al)(OH)2]
IMA status
  • Approved
  • Grandfathered
IMA symbol
Val
Discovered
1870
Also known as
  • Valleriiet

Where it forms, where it's found

Type locality
Aurora Mine
  1. Kaveltorp Mines
  2. Kopparberg
  3. Ljusnarsberg
  4. Örebro County
  5. Sweden
244recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789101 – 1.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Opaque
Colour
Dark gray-bronze-yellow
Streak
Black
Cleavage
Very Good

(0001)

Density
3.14 g/cm³

Optical

Pleochroism
Strong

Pale yellow to deep brown.

Anisotropism
Strong, golden yellow
Tropism
Anisotropic
Reflectance R%
(10.5,11.1) 400, (10.8,11.3) 420, (10.7,12.7) 440, (10.6,14.2) 460, (10.5,15.8) 480, (10.5,17.3) 500, (10.3,18.8) 520, (10.3,20.1) 540, (10.3,21.3) 560, (10.2,22.4) 580, (10.3,23.4) 600, (10.3,24.4) 620, (10.3,25.1) 640, (10.4,25.8) 660, (10.3,26.4) 680, (10.3,26.9) 700
Reflected-light panel
10.4 %anisotropic · dual curve
Specimen sRGB 122, 83, 44
White reference100 % reflector under same lamp
R₁ R₂
Mode
Anisotropism
Strong, golden yellow

Crystallography

Crystal system
Trigonal
Cell parameters
a = 64.46 Å · c = 34.10 Å
Z
390
Comment

Point Group: _3 2/m or 3m.; Space Group: R_3m or R3m.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
29CuCopperCopper263.546127.092
29.32%
26FeIronIron255.845111.690
25.77%
16SSulfurSulfur232.06064.120
14.79%
8OOxygenOxygen3.0615.99948.957
11.30%
13AlAluminiumAluminium1.5326.98241.282
9.53%
12MgMagnesiumMagnesium1.5324.30537.187
8.58%
1HHydrogenHydrogen3.061.0083.084
0.71%
Total433.413100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Ni
  • Ca
  • K
  • Na
  • Si

Synonyms

  • Valleriiet

In other languages

French
valleriite
German
Valleriit
Spanish
valleriíta
Italian
valleriite
Chinese
墨铜矿

Classification

Strunz
10th ed.

2.FD.30

  • 2Sulfides and SulfosaltsClass
  • 2.FSulfides of arsenic, alkalies; sulfides with halide, oxide, hydroxide, H2ODivision
  • 2.FDWith O, OH, H2OGroup
  • 2.FD.30ValleriiteSpecies
Dana
8th ed.

02.14.01.01

  • 02SulfidesClass
  • 02.14Hydroxysulfides and Hydrated SulfidesType
  • 02.14.01— unnamed intermediate level —Group
  • 02.14.01.01ValleriiteSpecies
CIM

4.7

  • 4OxysulphidesClass
  • 4.7— unnamed intermediate level —Group
  • 4.7ValleriiteSpecies

Group, growth & confusion

Often grow together
12 minerals

Literature, links & citation

Citations
  1. 1870Blomstrand, C. W. (1870) Om några nya svenska mineralier samt om magnetkisen sammansättning. Öfversigt af Kongl. vetenskaps-akademiens förhandlingar, P. A. Norstedt & Söner. 19-27
  2. 1933Foshag, W.F. (1933) New mineral names. American Mineralogist: 18: 222-224.
  3. 1939Hiller, J.E. (1939) Zur Kristallstruktur des Valleriits. Zeitschrift für Kristallographie: 101: 425-434.
  4. 1944Palache, Charles, Berman, Harry, Frondel, Clifford (1944) The System of Mineralogy (7th ed.) Vol. 1 - Elements, Sulfides, Sulfosalts, Oxides. John Wiley and Sons, New York.
  5. 1964Evans, H.T., Milton, C., Chao, E.C.T., Adler, I., Mead, C., Ingram, B., Berner, R.A. (1964) Valleriite and the new iron sulfide, mackinawite. U.S. Geological Survey Professional Paper, 475-D: 64-69.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Valleriite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/valleriite-4136},
  note      = {Accessed 2026-05-11}
}