Francoanellite

K3Al5(PO3OH)6(PO4)2 · 12H2O
IMA status
  • Approved
IMA symbol
Fan
Discovered
1976
Also known as
  • Francoanelliet
  • IMA1974-051

Where it forms, where it's found

Geological setting

Limestone cave.

Type locality
Grotte di Castellana
  1. Castellana Grotte
  2. Metropolitan City of Bari
  3. Apulia
  4. Italy

40.8756°, 17.1483°

10recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789101 – 2/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Yellowish white
Streak
White
Tenacity
waxy
Density
2.26 g/cm³

Optical

Optical type
Uniaxial (+)
Refractive index
1.51 – 1.515
Surface relief
Moderate
Principal indices
nω 1.510 · nε 1.515
Michel-Lévy diagramhighlighted lineδ = 0.0050
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]50 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation50 nm
Order1st order
XPL colour

Crystallography

Crystal system
Trigonal
Cell parameters
a = 8.71 Å · c = 82.5 Å
Z
6
Comment

Point Group: _3 2/m or 3m Space Group: R_3c or R3c (synthetic).

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen4415.999703.956
57.04%
15PPhosphorusPhosphorus830.974247.792
20.08%
13AlAluminiumAluminium526.982134.910
10.93%
19KPotassiumPotassium339.098117.294
9.50%
1HHydrogenHydrogen301.00830.240
2.45%
Total1234.192100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Francoanelliet
  • IMA1974-051

In other languages

German
Francoanellit · IMA 1974-051
Italian
Francoanellite
Chinese
磷铝钾石

Classification

Strunz
10th ed.

8.CH.25

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.CPhosphates without additional anions, with H2ODivision
  • 8.CHWith large and medium-sized cations, RO4:H2O < 1:1Group
  • 8.CH.25FrancoanelliteSpecies
Dana
8th ed.

39.03.05.02

  • 39Hydrated Acid Phosphates, Arsenates and VanadatesClass
  • 39.03MiscellaneousType
  • 39.03.05— unnamed intermediate level —Group
  • 39.03.05.02FrancoanelliteSpecies
CIM

19.8.8

  • 19PhosphatesClass
  • 19.8Phosphates of Al and other metalsGroup
  • 19.8.8FrancoanelliteSpecies

Group, growth & confusion

Often grow together
1 mineral

Literature, links & citation

Citations
  1. 1976Fleischer, Michael, Pabst, Adolf, Cabri, Louis J. (1976) New Mineral Names. American Mineralogist, 61 (9-10) 1053-1056
  2. 1976Balenzano, F., Dell´Anna, L., Di Pierro, M. (1976) Francoanellite, H6K3Al5(PO4)8·13H2O, a new mineral from the caves of Castellana, Puglia, southern Italy. Neues Jahrbuch für Mineralogie Monatshefte: 1976: 49-57.
  3. 1998Dick, S., Zeiske, T. (1998) Francoanellit K3Al5(HPO4)6(PO4)2·12H2O: struktur und synthese durch topochemische entwässerung von taranakit. Zeitschrift für Naturforschung B Chemical Science: 53: 711-719.
  4. 2005(2005) Francoanellite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Francoanellite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/francoanellite-1593},
  note      = {Accessed 2026-05-11}
}